The vapor pressures (VP) of several water-propanol (CH3CH₂CH₂OH) solutions were determined at various compositions, with the following data collected at 45°C: X H₂O Total VP (Torr) 74.0 0.15 0.37 0.54 77.3 80.2 81.6 80.6 0.69 0.83 78.2 1.00 71.9 a) Are solutions of water and propanol ideal? Explain. b) Are the interactive forces between propanol and water molecules weaker than, stronger than, or equal to the interactive forces between the pure substances? Explain. c) Predict the sign of AHsoln for water-propanol solutions. (Hint: think about deviation type) d) Which of the solutions in the data would have the lowest normal boiling point? Explain

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The vapor pressures (VP) of several water-propanol (CH3CH₂CH₂OH) solutions were
determined at various compositions, with the following data collected at 45°C:
X H₂O
0
Total VP (Torr) 74.0
0.15 0.37 0.54 0.69 0.83 1.00
77.3 80.2 81.6 80.6 78.2 71.9
a) Are solutions of water and propanol ideal? Explain.
b) Are the interactive forces between propanol and water molecules weaker than,
stronger than, or equal to the interactive forces between the pure substances? Explain.
c) Predict the sign of AHsoln for water-propanol solutions. (Hint: think about deviation
type)
d) Which of the solutions in the data would have the lowest normal boiling point?
Explain
Transcribed Image Text:The vapor pressures (VP) of several water-propanol (CH3CH₂CH₂OH) solutions were determined at various compositions, with the following data collected at 45°C: X H₂O 0 Total VP (Torr) 74.0 0.15 0.37 0.54 0.69 0.83 1.00 77.3 80.2 81.6 80.6 78.2 71.9 a) Are solutions of water and propanol ideal? Explain. b) Are the interactive forces between propanol and water molecules weaker than, stronger than, or equal to the interactive forces between the pure substances? Explain. c) Predict the sign of AHsoln for water-propanol solutions. (Hint: think about deviation type) d) Which of the solutions in the data would have the lowest normal boiling point? Explain
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