The total z component of the spin angular momentum operator for an N-electron system is N Ŝz total j=1 a) Show that 1 Visa(1) yısB(1)| v2|Y1sa(2) Vısß(2) || is an eigenfunction of Sz4otal· What is the eigenvalue? b) Show that Vısa(1) WisB(1) W2,¤(1) 1 V1sa(2) WisB(2) V2,¤(2) V3! Vısa(3) WısB(3) W2,¤(3) is an eigenfunction of Ŝz4otal. What is the eigenvalue?
The total z component of the spin angular momentum operator for an N-electron system is N Ŝz total j=1 a) Show that 1 Visa(1) yısB(1)| v2|Y1sa(2) Vısß(2) || is an eigenfunction of Sz4otal· What is the eigenvalue? b) Show that Vısa(1) WisB(1) W2,¤(1) 1 V1sa(2) WisB(2) V2,¤(2) V3! Vısa(3) WısB(3) W2,¤(3) is an eigenfunction of Ŝz4otal. What is the eigenvalue?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please show work for parts a and b with explanation thank you

Transcribed Image Text:The total z component of the spin angular momentum operator for an N-electron system is
N
Ŝ,stotal=
j=1
a) Show that
1Visa(1) yısB(1)|
v2|V1sa(2) yısß(2)
is an eigenfunction of Ŝ„total· What is the eigenvalue?
b) Show that
Visa(1) VisB(1) W2,a(1)
1
Vısa(2) Wısß(2) ¥2,¤(2)
V3!
V1,a(3) Yısß(3) V2,¤(3)
Y =
is an eigenfunction of Ŝ,total. What is the eigenvalue?
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