The table lists common half-reactions along with the standard reduction potential associated with each half-reaction. These standard reduction potentials are all relative to some standard. What is the standard (zero point)? If is positive for a half-reaction, what does it mean? If is negative for a half-reaction, what does it mean? Which species in table is mos
The table lists common half-reactions along with the standard reduction potential associated with each half-reaction. These standard reduction potentials are all relative to some standard. What is the standard (zero point)? If is positive for a half-reaction, what does it mean? If is negative for a half-reaction, what does it mean? Which species in table is mos
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The table lists common half-reactions along with the standard reduction potential associated with each half-reaction. These standard reduction potentials are all relative to some standard.
What is the standard (zero point)?
If is positive for a half-reaction, what does it mean?
If is negative for a half-reaction, what does it mean?
Which species in table is most easily reduced? Least easily reduced?
If the reverse of the half-reactions in the table are the oxidation half-reactions, how are standard oxidation potentials determined

Transcribed Image Text:TABLE 17.1
Standard Reduction Potentials at 25°C (298 K) for Many Common Half-Reactions
Half-Reaction
E* (V)
g° (V)
Half-Reaction
F; + 2e + 2F
Ag* +e + Ag"
Co +e + Co
HO, + 2H + 2e"
Ce*" + e → Ce"
O, + 2H,0 + 4e 40H
Cu* + 2e - Cu
Hg Cl; + 2e - 2Hg + 20
AgCl +e + Ag + C
so + 4H' + 2e" + H,SO, + H,0
Cu* + e Cu"
2.87
0.40
1.99
0.34
1.82
1.78
0.27
• 2H,0
0.22
1.70
0.20
PBO, + 4H* + So,- + 2e → PhSO, + 2H0
MnO, + 4H" + 3e → MnO, + 2H,0
2e + 2H* + 10, 10, + H,0
MnO, + 8H* + 5e + Mn* + 4H,0
Au+ + 3e Au
PbO, + 4H* + 2e + Pb* + 2H0
C, + 2e 2CI
Cr,0, + 14H + 6e¯ → 2Cr" + 7H;O
O, + 4H" + 4e 2H,0
MnO, + 4H* + 2e → Mn* + 2H,0
10, + 6H" + 5e -
Br, + 2e 2Br
VO," + 2H + e Vo + H,O
AuCl, + 3e → Au + 4CI
NO, + 4H* + 3e → NO + 2H,0
C1O, +e → CIO,
2Hg** + 2e -
Ag +e Ag
Hg,* + 2e → 2Hg
Fe* + e → Fe+
O, + 2H* + 2e H,O,
MnO, +e - MnO,
Iz + 2e 21
Cu" +e → Cu
1.69
0.16
2H* + 2e Hz
Fe* + 3e- Fe
Pb* + 2e
Sn* + 2e - Sn
Ni** + 2e Ni
PhSO, + 2e - Pb + So
Cd** + 2e Cd
Fe* + 2e -→ Fe
Cr* +e" Cr*
Cr* + 3e Cr
Zn + 2e Zn
2H,0 + 2e → Hạ + 20H
Mn** + 2e - Mn
Al" + 3e Al
H2 + 2e 2H
Mg* + 2e - Mg
La + 3e La
1.68
0.00
1.60
-0.036
1.51
- Pb
-0.13
1.50
-0.14
1.46
-0.23
1.36
-0.35
1.33
-0.40
1.23
-0.44
1.21
-0.50
→ Įl; + 3H¿0
1.20
-0.73
1.09
-0.76
1.00
-0.83
0.99
-1.18
0.96
-1.66
0.954
-2.23
0.91
-2.37
0.80
-2.37
0.80
Na* +e + Na
-2.71
Ca + 2e Ca
Ba* + 2e → Ba
K* +e + K
Li" +e + Li
0.77
-2.76
0.68
-2.90
0.56
-2.92
0.54
-3.05
0.52
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