The system(s) Raoult's Law is inapplicable for is/are? O c O C and D O B A and B O A

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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The system(s) Raoult's Law is inapplicable for is/are?
O c
O C and D
О в
A and B
O A
SUBMIT ANSWER
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DELL
Transcribed Image Text:500- 240 2.20 200 100- Q Zoom image The system(s) Raoult's Law is inapplicable for is/are? O c O C and D О в A and B O A SUBMIT ANSWER 74F Haze to search DELL
2 Edit
Question 23/39 Answer is mandatory
The following is Pxy diagrams for the four systems at T = 25°C:
A) Benzene-Formaldehyde, B) Benzene-Diethyl ketone, C) Water-Acetic acid, and D) Water Formic acid
800.00
Behzene-Formaldehyde
500.00
12.00
Benzene- Diethyl Ketone
40000
10.00
20000
100.00
4.00
400
0.00
020
1.00
020
40
.00
x Benzene
* Benzene
Water + Acetic acid
Water--Formid acid
3.20
3.50
100
2.30
4.5h
280
240
20
78 F Haze
ere to search
DELL
(ese anssa
(e nsseld
Transcribed Image Text:2 Edit Question 23/39 Answer is mandatory The following is Pxy diagrams for the four systems at T = 25°C: A) Benzene-Formaldehyde, B) Benzene-Diethyl ketone, C) Water-Acetic acid, and D) Water Formic acid 800.00 Behzene-Formaldehyde 500.00 12.00 Benzene- Diethyl Ketone 40000 10.00 20000 100.00 4.00 400 0.00 020 1.00 020 40 .00 x Benzene * Benzene Water + Acetic acid Water--Formid acid 3.20 3.50 100 2.30 4.5h 280 240 20 78 F Haze ere to search DELL (ese anssa (e nsseld
Expert Solution
Step 1

Explanation:

Raoult's is applicable to ideal solution. Azeotrope are real solution which shows positive and negative deviations from ideality. Hence, Raoult's law cannot be applicable to azeotrope solution.

It is observed that Figure C shows minimum boiling azeotrope and Figure D shows maximum boiling azeotrope. In both this case Raoult's law is inapplicable.

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