The standard enthalpies of formation of gaseous propyne1C3H42, propylene 1C3H62, and propane 1C3H82 are+185.4, +20.4, and -103.8 kJ>mol, respectively. (a) Calculatethe heat evolved per mole on combustion of each substance toyield CO21g2 and H2O1g2. (b) Calculate the heat evolved oncombustion of 1 kg of each substance. (c) Which is the mostefficient fuel in terms of heat evolved per unit mass?
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
The standard enthalpies of formation of gaseous propyne
1C3H42, propylene 1C3H62, and propane 1C3H82 are
+185.4, +20.4, and -103.8 kJ>mol, respectively. (a) Calculate
the heat evolved per mole on combustion of each substance to
yield CO21g2 and H2O1g2. (b) Calculate the heat evolved on
combustion of 1 kg of each substance. (c) Which is the most
efficient fuel in terms of heat evolved per unit mass?
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