The reaction C,H, (g) → 2C,H,(g) has an activation energy of 262 kJ/mol. At 600.0 K, the rate constant, k, is 6.1 × 10-8 s-1. What is the value of the rate constant at 745.0 K? k =

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**Chemical Reaction and Activation Energy Calculation**

The given reaction is:

\[ \text{C}_4\text{H}_8\text{(g)} \rightarrow 2 \, \text{C}_2\text{H}_4\text{(g)} \]

This reaction has an activation energy of 262 kJ/mol. At a temperature of 600.0 K, the rate constant (\(k\)) is \(6.1 \times 10^{-8} \, \text{s}^{-1}\). We are tasked with finding the value of the rate constant at 745.0 K.

**Formula to Use:**

The relation between the rate constants at two different temperatures can be determined using the Arrhenius equation:

\[ k = A \, e^{-\frac{E_a}{RT}} \]

Where:
- \(k\) is the rate constant,
- \(A\) is the pre-exponential factor,
- \(E_a\) is the activation energy,
- \(R\) is the gas constant (8.314 J/mol·K),
- \(T\) is the temperature in Kelvin.

**Comparison of Rate Constants:**

To find the rate constant at the new temperature (745.0 K), the Arrhenius equation can be rearranged to the following form for practical use:

\[ \ln \left( \frac{k_2}{k_1} \right) = -\frac{E_a}{R} \left( \frac{1}{T_2} - \frac{1}{T_1} \right) \]

Where:
- \(k_1\) and \(k_2\) are the rate constants at temperatures \(T_1\) and \(T_2\) respectively,
- \(T_1\) is 600.0 K,
- \(T_2\) is 745.0 K.

**Calculate \(k\):**

Insert the given values to solve for \(k\) at 745.0 K in the provided box.

\[ k = \, \square \, \text{s}^{-1} \]
Transcribed Image Text:**Chemical Reaction and Activation Energy Calculation** The given reaction is: \[ \text{C}_4\text{H}_8\text{(g)} \rightarrow 2 \, \text{C}_2\text{H}_4\text{(g)} \] This reaction has an activation energy of 262 kJ/mol. At a temperature of 600.0 K, the rate constant (\(k\)) is \(6.1 \times 10^{-8} \, \text{s}^{-1}\). We are tasked with finding the value of the rate constant at 745.0 K. **Formula to Use:** The relation between the rate constants at two different temperatures can be determined using the Arrhenius equation: \[ k = A \, e^{-\frac{E_a}{RT}} \] Where: - \(k\) is the rate constant, - \(A\) is the pre-exponential factor, - \(E_a\) is the activation energy, - \(R\) is the gas constant (8.314 J/mol·K), - \(T\) is the temperature in Kelvin. **Comparison of Rate Constants:** To find the rate constant at the new temperature (745.0 K), the Arrhenius equation can be rearranged to the following form for practical use: \[ \ln \left( \frac{k_2}{k_1} \right) = -\frac{E_a}{R} \left( \frac{1}{T_2} - \frac{1}{T_1} \right) \] Where: - \(k_1\) and \(k_2\) are the rate constants at temperatures \(T_1\) and \(T_2\) respectively, - \(T_1\) is 600.0 K, - \(T_2\) is 745.0 K. **Calculate \(k\):** Insert the given values to solve for \(k\) at 745.0 K in the provided box. \[ k = \, \square \, \text{s}^{-1} \]
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