The Ostwald process for the commercial production of nitric acid from ammonia and oxygen involves the following steps: 4NH3(g) + 50₂(8) →→ 4NO(g) + 6H₂O(g) 2NO(g) + O₂(g) →→ 2NO₂(g) 3NO₂(g) + H₂O(1) →→→→→ 2HNO3(aq) + NO(g) a. Use the values of AH in Appendix 4 to calculate the value of AH for each of the preceding reactions. b. Write the overall equation for the production of nitric acid by the Ostwald process by combining the preceding equa- tions. (Water is also a product.) Is the overall reaction exothermic or endothermic?
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
Help with question 81, explain in detail how to find b is enthalpy value and the overall equation please.
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(g) +
a.
(g) +
N OH
b. Ca3(PO4)₂ (s) + 3H₂SO4(1) →→→→→3CaSO4(s) + 2H3PO4 (1)
c. NH3(g) + HCl(g) →→→→NH₂Cl(s)
(1) +
80. Use the values of AHF in Appendix 4 to calculate AHⓇ for the
following reactions. (See Exercise 79.)
(g)
b. SiCl4 (1) + 2H₂O(1)
c. MgO(s) + H₂O(1)
(g) +
4NH3(g) + 5O₂(g)
2NO(g) + O₂(g)
3NO₂(g) + H₂O(1)
SiO₂ (s) + 4HCl(aa)
Mg(OH)₂ (s) 315/ 1206
(g) +
81. The Ostwald process for the commercial production of nitric
acid from ammonia and oxygen involves the following steps:
4NO(g) + 6H₂O(g)
2NO₂(g)
2HNO3(aq) + NO(g)
a. Use the values of AH in Appendix 4 to calculate the
value of AH° for each of the preceding reactions.
(g)
b. Write the overall equation for the production of nitric acid
by the Ostwald process by combining the preceding equa-
tions. (Water is also a product.) Is the overall reaction
exothermic or endothermic?
82. Calculate AH for each of the following reactions using the
data in Appendix 4:
4Na(s) + O₂(g) →→→→ 2Na₂O(s)
2Na(s) + 2H₂O(1) →→→→ 2NaOH(aq) + H₂(g)
2Na(s) + CO₂(g) →→→ Na₂O(s) + CO(g)
3A1(s) + 3NH₂C1O4(s) →→→→
Explain why a water or carbon dioxide fire extinguisher might
not be effective in putting out a sodium fire.
83. The reusable booster rockets of the space shuttle use a mixture
of aluminum and ammonium perchlorate as fuel. A possible
reaction is
Calculate AH° for this reaction.
Al2O3(s) + AIC13(s) + 3NO(g) + 6H₂O(g)
84. The space shuttle Orbiter utilizes the oxidation of methylhy-
drazine by dinitrogen tetroxide for propulsion:
4N₂H3CH₂(1) + 5N₂O4(1) - 12H₂O(g) + 9N₂(g) + 4CO₂(g)
Calculate AH° for this reaction"
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