The normalised radial component of the wavefunction for the ground state of hydrogen is given by (n = 1,1 = 0, m = 0) 1 V100 (") -e(-r/ao) %3D where ao is the Bohr radius, qe is the electronic charge, u is the reduced mass and the other symbols have their standard meanings. Find an expression for the radial position expectation value (r) (in symbols).
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- Show that the uncertainty principle can be expressed in the form ∆L ∆θ ≥ h/2, where θ is the angle and L the angular momentum. For what uncertainty in L will the angular position of a particle be completely undetermined?Compute and compare the electrostatic and gravita- tional forces in the classical hydrogen atom, assuming a radius 5.3 × 10-¹¹ m.Complete the derivation of E = Taking the derivatives we find (Use the following as necessary: k₁, K₂ K3, and 4.) +- ( ²) (²) v² = SO - #2² - = 2m so the Schrödinger equation becomes (Use the following as necessary: K₁, K₂, K3, ħ, m and p.) 亢 2mm(K² +K ² + K² v k₁ = E = = EU The quantum numbers n, are related to k, by (Use the following as necessary: n, and L₁.) лħ n₂ π²h² 2m √2m h²²/0₁ 2m X + + by substituting the wave function (x, y, z) = A sin(kx) sin(k₂y) sin(kz) into - 13³3). X What is the origin of the three quantum numbers? O the Schrödinger equation O the Pauli exclusion principle O the uncertainty principle Ⓒthe three boundary conditions 2² 7²4 = E4. 2m
- The wave function for hydrogen in the 1s state may be expressed as Psi(r) = Ae−r/a0. Determine the most probable value for the location of the electron when the atom is in this state. (Use the following as necessary: A, a0) where A = 1/sqrt(pi*a03)An electron in a hydrogen atom is approximated by a one-dimensional infinite square well potential. The normalised wavefunction of an electron in a stationary state is defined as *(x) = √√ sin (""). L where n is the principal quantum number and L is the width of the potential. The width of the potential is L = 1 x 10-¹0 m. (a) Explain the meaning of the term normalised wavefunction and why normalisation is important. (b) Use the wavefunction defined above with n = 2 to determine the probability that an electron in the first excited state will be found in the range between x = 0 and x = 1 × 10-¹¹ m. Use an appropriate trigonometric identity to simplify your calculation. (c) Use the time-independent Schrödinger Equation and the wavefunction defined above to find the energies of the first two stationary states. You may assume that the electron is trapped in a potential defined as V(x) = 0 for 0≤x≤L ∞ for elsewhere.Explain each step