The MS and 13C NMR spectra for two constitutional isomers with 4 degrees of unsaturation are shown below. Determine the molecular structures of the two constitutional isomers.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The MS and 13C NMR spectra for two constitutional isomers with 4 degrees of unsaturation are shown below. Determine the molecular structures of the two constitutional isomers.

ISOMER A
ISOMER B
100-
100
80-
80-
60-
60-
40 -
40-
MT. 140
20-
20-
75
100
125
25
50
75
100
125
m/z
m/z
m? pautas total
2 peaks
3 peales tolad
200
180
160
140
120
100
80
60
40
20
200
180
160
140
120
100
80
60
40
20
CDS-00-007
ppm
Cos-00-e86
pm
Relative Intensity
Relative Intensity
Transcribed Image Text:ISOMER A ISOMER B 100- 100 80- 80- 60- 60- 40 - 40- MT. 140 20- 20- 75 100 125 25 50 75 100 125 m/z m/z m? pautas total 2 peaks 3 peales tolad 200 180 160 140 120 100 80 60 40 20 200 180 160 140 120 100 80 60 40 20 CDS-00-007 ppm Cos-00-e86 pm Relative Intensity Relative Intensity
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