The isomerization reaction: H3C-NEC → H3C-C=N obeys the rate law: rate= K[H3C-N=C] with k= 6.6 x 104 s-1 at 500 K and activation energy E₂ = 161 kJ/mol. Calculate AH if the C-N bond enthalpy is 305 kJ/mol and the C-C bond enthalpy is 348 kJ/mol 1. 13 kJ/mol 2. -23 kJ/mol 3. 33 kJ/mol 4. -43 kJ/mol 53 kl/mol
Catalysis and Enzymatic Reactions
Catalysis is the kind of chemical reaction in which the rate (speed) of a reaction is enhanced by the catalyst which is not consumed during the process of reaction and afterward it is removed when the catalyst is not used to make up the impurity in the product. The enzymatic reaction is the reaction that is catalyzed via enzymes.
Lock And Key Model
The lock-and-key model is used to describe the catalytic enzyme activity, based on the interaction between enzyme and substrate. This model considers the lock as an enzyme and the key as a substrate to explain this model. The concept of how a unique distinct key only can have the access to open a particular lock resembles how the specific substrate can only fit into the particular active site of the enzyme. This is significant in understanding the intermolecular interaction between proteins and plays a vital role in drug interaction.
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The isomerization reaction:
H3C-NEC → H3C-C=N
obeys the rate law: rate = K[H3C-N=C]
with k= 6.6 x 104 s-1 at 500 K and
activation energy E₂ = 161 kJ/mol.
Calculate AH if the C-N bond enthalpy is
305 kJ/mol and the C-C bond enthalpy is
348 kJ/mol
13 kJ/mol
-23 kJ/mol
3. 33 kJ/mol
4.
-43 kJ/mol
53 kl/mol](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fcd811631-ea8b-4cd0-af7f-8f78d10f5237%2Fee3e509d-904e-4621-9950-049d430fa117%2Fjnx09na_processed.jpeg&w=3840&q=75)
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