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The IR spectrum of [Co(CO)4H] has bands at 2121, 2062, 2043 and 1934 cm-1. Upon deuteration of the complex, the resultant IR spectrum shows bands at 2120, 2058, 2043, 1396 cm-1. i) the intensity of an IR band? State the selection rule for an IR active transition. What factor influences ii) Using the data above explain which of the IR bands for [Co(CO)4H] is due to the v(Co-H) stretch. Show your working.

The IR spectrum of [Co(CO)4H] has bands at 2121, 2062, 2043 and 1934 cm-1. Upon deuteration of the complex, the resultant IR spectrum shows bands at 2120, 2058, 2043, 1396 cm-1. i) the intensity of an IR band? State the selection rule for an IR active transition. What factor influences ii) Using the data above explain which of the IR bands for [Co(CO)4H] is due to the v(Co-H) stretch. Show your working.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The IR spectrum of [Co(CO)4H] has bands at 2121, 2062, 2043 and 1934 cm-1. Upon deuteration of the complex, the resultant IR spectrum shows bands at 2120, 2058, 2043, 1396 cm-1. i) the intensity of an IR band? State the selection rule for an IR active transition. What factor influences ii) Using the data above explain which of the IR bands for [Co(CO)4H] is due to the v(Co-H) stretch. Show your working.
Transcribed Image Text:The IR spectrum of [Co(CO)4H] has bands at 2121, 2062, 2043 and 1934 cm-1. Upon deuteration of the complex, the resultant IR spectrum shows bands at 2120, 2058, 2043, 1396 cm-1. i) the intensity of an IR band? State the selection rule for an IR active transition. What factor influences ii) Using the data above explain which of the IR bands for [Co(CO)4H] is due to the v(Co-H) stretch. Show your working.
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