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The reaction of (Ti(co).]* and chlorotriphenylmethane, Ph,CCI, results in rapid oxidation of (Ti(CO)o] to afford a trityltitanium tetracarbonyl complex. On the basis of the IR spectrum (v(CO)): 1932, 1810 cm) acquired in THE solution, is this complex expected to exhibit a square planar or a square pyramidal arrangement of four CO ligands bound to titanium? Does the spectrum rule out either of these possible geometries? Show all work, including calculations, to justify your answer. 0.8- 0.6 0.4 - 0.2 0.0 2000 1900 1800 1700 1600 Wavenumbers

The reaction of (Ti(co).]* and chlorotriphenylmethane, Ph,CCI, results in rapid oxidation of (Ti(CO)o] to afford a trityltitanium tetracarbonyl complex. On the basis of the IR spectrum (v(CO)): 1932, 1810 cm) acquired in THE solution, is this complex expected to exhibit a square planar or a square pyramidal arrangement of four CO ligands bound to titanium? Does the spectrum rule out either of these possible geometries? Show all work, including calculations, to justify your answer. 0.8- 0.6 0.4 - 0.2 0.0 2000 1900 1800 1700 1600 Wavenumbers

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The reaction of (Ti(co).]* and chlorotriphenylmethane, Ph,CCI, results in rapid oxidation of (Ti(CO)o] to afford a trityltitanium tetracarbonyl complex. On the basis of the IR spectrum (v(CO)): 1932, 1810 cm) acquired in THE solution, is this complex expected to exhibit a square planar or a square pyramidal arrangement of four CO ligands bound to titanium? Does the spectrum rule out either of these possible geometries? Show all work, including calculations, to justify your answer. 0.8- 0.6 0.4 - 0.2 0.0 2000 1900 1800 1700 1600 Wavenumbers
Transcribed Image Text:The reaction of (Ti(co).]* and chlorotriphenylmethane, Ph,CCI, results in rapid oxidation of (Ti(CO)o] to afford a trityltitanium tetracarbonyl complex. On the basis of the IR spectrum (v(CO)): 1932, 1810 cm) acquired in THE solution, is this complex expected to exhibit a square planar or a square pyramidal arrangement of four CO ligands bound to titanium? Does the spectrum rule out either of these possible geometries? Show all work, including calculations, to justify your answer. 0.8- 0.6 0.4 - 0.2 0.0 2000 1900 1800 1700 1600 Wavenumbers
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