The H NMR, 13C NMR and mass spectra of an unknown compound provide the following information: Proton NMR signals: Triplet at 1.3 ppm, ratio = 3 Multiplet at 1.9 ppm, ratio = 2 Triplet at 2.8 ppm, ratio = 2 Doublet at 7.1, ratio = 2 Doublet at 7.4, ratio = 2 Carbon NMR signals: 7 separate signals indicating the presence of 9 carbon atoms Mass spectrum: M+ = 198; M+2% D 200; ratio 1:1 What is this unknown compound? 2-Bromo-1-methylbenzene O 1-Propylbenzene O 2,4,6-Trichloro-1-ethylbenzene 4-Bromo-1-propylbenzene O 1-Amino-4-bromobenzene
The H NMR, 13C NMR and mass spectra of an unknown compound provide the following information: Proton NMR signals: Triplet at 1.3 ppm, ratio = 3 Multiplet at 1.9 ppm, ratio = 2 Triplet at 2.8 ppm, ratio = 2 Doublet at 7.1, ratio = 2 Doublet at 7.4, ratio = 2 Carbon NMR signals: 7 separate signals indicating the presence of 9 carbon atoms Mass spectrum: M+ = 198; M+2% D 200; ratio 1:1 What is this unknown compound? 2-Bromo-1-methylbenzene O 1-Propylbenzene O 2,4,6-Trichloro-1-ethylbenzene 4-Bromo-1-propylbenzene O 1-Amino-4-bromobenzene
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![The H NMR, 13C NMR and mass spectra of an unknown compound provide the following information:
Proton NMR signals:
Triplet at 1.3 ppm, ratio = 3
Multiplet at 1.9 ppm, ratio = 2
Triplet at 2.8
ppm,
ratio = 2
Doublet at 7.1, ratio = 2
Doublet at 7.4, ratio = 2
Carbon NMR signals:
7 separate signals indicating the presence of 9 carbon atoms
Mass spectrum:
M+ = 198; M+2 = 200; ratio 1:1
What is this unknown compound?
2-Bromo-1-methylbenzene
O 1-Propylbenzene
O 2,4,6-Trichloro-1-ethylbenzene
O 4-Bromo-1-propylbenzene
O 1-Amino-4-bromobenzene](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F450044ef-db4b-4b73-a24e-98f3627ca204%2F81443bba-fb7a-4bc7-a1d6-406298ce5565%2Fxspre0g_processed.jpeg&w=3840&q=75)
Transcribed Image Text:The H NMR, 13C NMR and mass spectra of an unknown compound provide the following information:
Proton NMR signals:
Triplet at 1.3 ppm, ratio = 3
Multiplet at 1.9 ppm, ratio = 2
Triplet at 2.8
ppm,
ratio = 2
Doublet at 7.1, ratio = 2
Doublet at 7.4, ratio = 2
Carbon NMR signals:
7 separate signals indicating the presence of 9 carbon atoms
Mass spectrum:
M+ = 198; M+2 = 200; ratio 1:1
What is this unknown compound?
2-Bromo-1-methylbenzene
O 1-Propylbenzene
O 2,4,6-Trichloro-1-ethylbenzene
O 4-Bromo-1-propylbenzene
O 1-Amino-4-bromobenzene
![What is the correct order of reactivity, going from lowest to highest?
O Carboxylate anion -> Amide -> Ester -> Anhydride -> Acid chloride
Amide -> Ester -> Anhdryde -> Acid chloride -> Carboxylate anion
O Carboxylate anion -> Anhydride -> Ester -> Amide -> Acid chloride
O Ester -> Acid chloride -> Carboxylate anion -> Amide -> Anhydride
O Carboxylate anion -> Amide -> Ester -> Acid chloride -> Anhydride](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F450044ef-db4b-4b73-a24e-98f3627ca204%2F81443bba-fb7a-4bc7-a1d6-406298ce5565%2Fn7bvz6b_processed.jpeg&w=3840&q=75)
Transcribed Image Text:What is the correct order of reactivity, going from lowest to highest?
O Carboxylate anion -> Amide -> Ester -> Anhydride -> Acid chloride
Amide -> Ester -> Anhdryde -> Acid chloride -> Carboxylate anion
O Carboxylate anion -> Anhydride -> Ester -> Amide -> Acid chloride
O Ester -> Acid chloride -> Carboxylate anion -> Amide -> Anhydride
O Carboxylate anion -> Amide -> Ester -> Acid chloride -> Anhydride
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