The formation of orthonitroaniline is from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia.C6H4ClNO2 + 2NH3 → O2NC6H4NH2 + NH4ClThis liquid-phase reaction is first order in both ONCB and ammonia with k = 0.0017 m3/kmol•min at 188 oC with E = 11273 cal/mol. The initial entering concentration of ONCB and ammonia are 1.8 kmol/m3 and 6.6 kmol/m3, respectively. Gas constant: R = 1.987 cal/(K∙mol). (a) Write the rate law for the rate of disappearance of ONCB in terms of molar concentration.(b) Set up a stoichiometric table for a flow system with respect to the flow rate.(c) Write –rA solely as a function of conversion.(d) What is the initial rate of reaction (X = 0) at 188 oC?(e) What is the initial rate of reaction (X = 0) at 25 oC?

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Introduction to Chemical Engineering Thermodynamics

8th Edition

ISBN:9781259696527

Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Chapter1: Introduction

Section: Chapter Questions

Problem 1.1P

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The formation of orthonitroaniline is from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia.

C₆H₄ClNO₂ + 2NH₃ → O₂NC₆H₄NH₂ + NH₄Cl

This liquid-phase reaction is first order in both ONCB and ammonia with k = 0.0017 m³/kmol•min at 188 ^oC with E = 11273 cal/mol. The initial entering concentration of ONCB and ammonia are 1.8 kmol/m³ and 6.6 kmol/m³, respectively. Gas constant: R = 1.987 cal/(K∙mol).

(a) Write the rate law for the rate of disappearance of ONCB in terms of molar concentration.

(b) Set up a stoichiometric table for a flow system with respect to the flow rate.

(d) What is the initial rate of reaction (X = 0) at 188 ^oC?

(e) What is the initial rate of reaction (X = 0) at 25 ^oC?

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