The following two compounds are constitutional isomers. Identify which of these is expected to be more acidic, and explain your choice. OH مل H₂C OH A is the stronger acid because the negative charge in the conjugate base is adjacent to an electron-withdrawing group, making it the LESS stable conjugate base. O A is the stronger acid because the negative charge in the conjugate base is adjacent to an electron-withdrawing group, making it the MORE stable conjugate base. O B is the stronger acid because the negative charge in stable conjugate base. the conjugate base is delocalized by resonance, making it the MORE B is the stronger acid because the negative charge in the conjugate base is delocalized by resonance, making it the LESS stable conjugate base.
The following two compounds are constitutional isomers. Identify which of these is expected to be more acidic, and explain your choice. OH مل H₂C OH A is the stronger acid because the negative charge in the conjugate base is adjacent to an electron-withdrawing group, making it the LESS stable conjugate base. O A is the stronger acid because the negative charge in the conjugate base is adjacent to an electron-withdrawing group, making it the MORE stable conjugate base. O B is the stronger acid because the negative charge in stable conjugate base. the conjugate base is delocalized by resonance, making it the MORE B is the stronger acid because the negative charge in the conjugate base is delocalized by resonance, making it the LESS stable conjugate base.
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:The following two compounds are constitutional isomers. Identify which of these is expected to be more acidic, and explain your
choice.
OH
مل
H₂C
OH
A is the stronger acid because the negative charge in the conjugate base is adjacent to an electron-withdrawing group,
making it the LESS stable conjugate base.
O A is the stronger acid because the negative charge in the conjugate base is adjacent to an electron-withdrawing group,
making it the MORE stable conjugate base.
O B is the stronger acid because the negative charge in
stable conjugate base.
the conjugate base is delocalized by resonance, making it the MORE
B is the stronger acid because the negative charge in the conjugate base is delocalized by resonance, making it the LESS
stable conjugate base.
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