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The following three-step mechanism has been proposed for the reaction between chlorine and chloroform. Step 1: Cl2 (g) ↔ 2 Cl (g) Step 2: Cl (g) + CHCl3 (g) ↔ HCl (g) + CCl3 (g) Step 3: CCl3 (g) + Cl (g) ↔ CCl4 (g) The numerical values of a few of the rate constants for these steps are: k1 = 4.8 x 103, k-1 = 3.6 x 103, k2 = 1.3 x 10-2, k3 = 2.7 x 102 Give the overall chemical reaction. Derive the rate law and the magnitude of k for the overall reaction.

The following three-step mechanism has been proposed for the reaction between chlorine and chloroform. Step 1: Cl2 (g) ↔ 2 Cl (g) Step 2: Cl (g) + CHCl3 (g) ↔ HCl (g) + CCl3 (g) Step 3: CCl3 (g) + Cl (g) ↔ CCl4 (g) The numerical values of a few of the rate constants for these steps are: k1 = 4.8 x 103, k-1 = 3.6 x 103, k2 = 1.3 x 10-2, k3 = 2.7 x 102 Give the overall chemical reaction. Derive the rate law and the magnitude of k for the overall reaction.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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  1. The following three-step mechanism has been proposed for the reaction between chlorine and chloroform.

Step 1: Cl2 (g) ↔ 2 Cl (g)

Step 2: Cl (g) + CHCl3 (g) ↔ HCl (g) + CCl3 (g)

Step 3: CCl3 (g) + Cl (g) ↔ CCl4 (g)

The numerical values of a few of the rate constants for these steps are:

k1 = 4.8 x 103, k-1 = 3.6 x 103, k2 = 1.3 x 10-2, k3 = 2.7 x 102

    1. Give the overall chemical reaction.

 

 

 

    1. Derive the rate law and the magnitude of k for the overall reaction.
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