The following temperature-composition data were obtained for a mixture of octane (0) and toluene (T) at 760 Torr, where x is the mole fraction in the liquid and ythe mole fraction in the vapour at equilibrium .θ/°C    110.9    112.0    114.0    115.8    117.3    119.0    120.0    123.0Xr         0.908    0.795     0.615    0.527   0.408     0.300    0.203    0.097YT         0.923    0.836     0.698   0.624    0.527     0.410    0.297    0.164The boiling points are 110.6 °C for toluene and 125.6 °C for octane. Plot the temperatur-composition diagram of the mixture . What is the composition of the vapour in equilibrium with the liquid of composition (a) XT = 0.250 and (b) xO = 0.250?

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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The following temperature-composition data were obtained for a mixture of octane (0) and toluene (T) at 760 Torr, where x is the mole fraction in the liquid and ythe mole fraction in the vapour at equilibrium .
θ/°C    110.9    112.0    114.0    115.8    117.3    119.0    120.0    123.0
Xr         0.908    0.795     0.615    0.527   0.408     0.300    0.203    0.097
YT         0.923    0.836     0.698   0.624    0.527     0.410    0.297    0.164
The boiling points are 110.6 °C for toluene and 125.6 °C for octane. Plot the temperatur-composition diagram of the mixture . What is the composition of the vapour in equilibrium with the liquid of composition (a) XT = 0.250 and (b) xO = 0.250?

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