The following molecule has a stereoisomer which is referred to as its enantiomer H₂ OH CH3 C- C CH2 H₂ H CH₂ H₂C CH3 Draw a representation of this molecule's stereoisomer in the box below Draw only one molecule in each drawing box. Compound #1
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- (b) For each of the following pairs of structural formulas, indicate whether the two represent identical molecular species, constitutional isomers, enantiomers, or diastereomers. HOW HO HOlim Br Br H Br CH3 H Cl- H Br H. Cl CH3 CI H Cl H, H Cl OH Br Br6. For each pair of compounds below determine whether they represent the same molecule, enantiomers, or diastereomers. CH H₂N H CH J OllinO 2||2 COOH C OH CH₂ OH NH₂ CH, COOH CH3 HO H₂N CH₂4 CH CCC COOH OH NH₂ NIIIIIC CH₂ H CH3 CH3 H₂N HO H₂N COOH CH OH 5- O J CH3 COOH O H CH₂ H COOH HO CH CH₂4 HOOC COOH ........ OH JCC H NH₂ NH₂ CH₂Compounds 1 and 2 were prepared, and the difference in their heats of combustion was found to be 17.2 kJ/mol (J. Am. Chem. Soc. 1961, 83, 606-614): H H 1 Shown below are the lowest-energy conformations of compounds 1 and 2. Identify which drawing matches which compound, and identify which compound has the larger heat of combustion. H H H H |||I 2 H 4 H H The first drawing is compound 1, and compound 1 has a larger heat of combustion because it is the less stable compound. O The first drawing is compound 2, and compound 2 has a larger heat of combustion because it is the less stable compound. The first drawing is compound 2, and compound 2 has a larger heat of combustion because it is the more stable compound. The first drawing is compound 1, and compound 1 has a larger heat of combustion because it is the more stable compound.
- Identify the stereochemical configuration of this compound. SH CH3 O R S1E.) Which of the following two conformers is lower in energy? Both conformers are of equal enery O A Conformer A is lower in energy. B Conformer B is lower in energy. It cannot be determinedFor each of the following pairs of molecules, classify them as either: enantiomers, diastereomers, identical compounds, or constitutional isomers.
- What are the relative energy levels of the three staggered conformations of 2,3-dimethylbutane when looking down the C2-C3 bond? Me Me H Me Me Me Me Me. Me Conformation: 191 1ක් පුදා H Me Me Me H H H A B C Me A is the highest energy conformation and C is the lowest (energy level of B is in between the two) O A and B are equal energy, and C is the highest energy conformation A and B are equal energy, and C is the lowest energy conformation C is the highest energy conformation and A is the lowest (energy level of B is in between the two) O B is the highest energy conformation and C is the lowest (energy level of A is in between the two)Determine the relationship between the isomers of each pair of molecules. Identify whether they are constitutional isomers or conformational isomers or enantiomers or diastereoisomers.Shown is one isomer of 2,4-dibromo-1,3,5-triethylcyclohexane. Draw the most stable achiral stereoisomer of this compound, in its most stable conformation.
- Stereochemistry: Three possible answers- diastereomers, enantiomers OH CH₂OH I -c=0 21108 1101 41745 HOR CH₂OH IL Но CH₂OH TIL a. Compounds I and III have this relationship with each other: enantiomers b. Compounds II and IV have this relationship with each other: c. Compounds I and II have this relationship with each other: d. *Draw one structure that is a stereoisomer of II, but neither a diastereomer nor an enantiomer. (more than one correct answer)How many enantiomers does the following molecule have? (And, yes it is a trick question.) I NH₂ H3C. TC C OH NH₂ OH CH3Draw and name the six isomeric cyclopentane of molecular formula C7H14. These will include four constitutional isomers, of which two show geometric (cis-trans) stereoisomerism.
