The following mechanism is proposed for this reaction, so the steps are all elementary steps. N,O5 NO2 +NO3 k_1 k2 NO2 +NO3 NO + O2 + NO2 k3 NO +N,O5 3NO2 Warning: Elementary step 2 cannot be "simplified" by NO2 because an elementary act reflects the microscopic reality. We can verify that the balance equation corresponding to this mechanism is correct: 2 N2O5(g) → 4 NO2+ O2(g). a) Define what is an elementary reaction/step and the consequences in kinetics d[02] b) Using the given mechanism, express

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The following mechanism is proposed for this reaction, so the steps are all elementary steps.
k
N,O5
NO2 +NO3
k2
NO2 +NO3
NO + O2 + NO2
k3
NO +N2O5
3NO2
Warning: Elementary step 2 cannot be "simplified" by NO2 because an elementary act
reflects the microscopic reality.
We can verify that the balance equation corresponding to this mechanism is correct:
2 N2O5(g)
→ 4 NO2+ O2(g).
a) Define what is an elementary reaction/step and the consequences in kinetics
d[02]
b) Using the given mechanism, express
dt
Transcribed Image Text:The following mechanism is proposed for this reaction, so the steps are all elementary steps. k N,O5 NO2 +NO3 k2 NO2 +NO3 NO + O2 + NO2 k3 NO +N2O5 3NO2 Warning: Elementary step 2 cannot be "simplified" by NO2 because an elementary act reflects the microscopic reality. We can verify that the balance equation corresponding to this mechanism is correct: 2 N2O5(g) → 4 NO2+ O2(g). a) Define what is an elementary reaction/step and the consequences in kinetics d[02] b) Using the given mechanism, express dt
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