The following initial rate data are for the reaction of hypochlorite ion with iodide ion in 1 M aqueous hydroxide solution:\[\text{OCl}^- + \text{I}^- \rightarrow \text{OI}^- + \text{Cl}^-\]| Experiment | [OCl⁻]₀, M | [I⁻]₀, M | Initial Rate, M · s⁻¹ ||------------|------------|----------|----------------------|| 1 | 0.00231 | 0.00721 | 1.10 × 10⁻³ || 2 | 0.00231 | 0.0144 | 2.20 × 10⁻³ || 3 | 0.00462 | 0.00721 | 2.20 × 10⁻³ || 4 | 0.00462 | 0.0144 | 4.39 × 10⁻³ |Complete the rate law for this reaction in the box below.Use the form \( k[A]^m[B]^n \), where '1' is understood for \( m \) or \( n \) and concentrations taken to the zero power do not appear. Don’t enter 1 for \( m \) or \( n \).Rate = \_\_\_\_\_\_\( k = \) \_\_\_\_\_\_ M⁻¹ · s⁻¹

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Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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The following initial rate data are for the reaction of hypochlorite ion with iodide ion in 1 M aqueous hydroxide solution:

\[
\text{OCl}^- + \text{I}^- \rightarrow \text{OI}^- + \text{Cl}^-
\]

| Experiment | [OCl⁻]₀, M | [I⁻]₀, M | Initial Rate, M · s⁻¹ |
|------------|------------|----------|----------------------|
| 1 | 0.00231 | 0.00721 | 1.10 × 10⁻³ |
| 2 | 0.00231 | 0.0144 | 2.20 × 10⁻³ |
| 3 | 0.00462 | 0.00721 | 2.20 × 10⁻³ |
| 4 | 0.00462 | 0.0144 | 4.39 × 10⁻³ |

Complete the rate law for this reaction in the box below.

Use the form \( k[A]^m[B]^n \), where '1' is understood for \( m \) or \( n \) and concentrations taken to the zero power do not appear. Don’t enter 1 for \( m \) or \( n \).

Rate = \_\_\_\_\_\_

\( k = \) \_\_\_\_\_\_ M⁻¹ · s⁻¹

Expert Solution

Step 1: Defining the order of reaction

Answer:

Power of concentration term of a reactant in the rate law is equal to the order of reaction with respect to that reactant and overall order of the reaction will be equal to the sum of the powers of all the concentration terms.

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