The following equilibrium constants have been determined for hydrosulfuric acid at 25ºC: H2S(aq) ⇌ H+(aq)  +  HS–(aq)            K′c = 9.5 × 10–8 HS–(aq) ⇌ H+(aq)  +  S2–(aq)             K″c = 1.0 × 10–19 Calculate the equilibrium constant for the following reaction at the same temperature.  H2S(aq) ⇌ 2H+(aq)  +  S2–(aq)

Chemistry: Principles and Reactions
8th Edition
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Author:William L. Masterton, Cecile N. Hurley
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Chapter12: Gaseous Chemical Equilibrium
Section: Chapter Questions
Problem 20QAP: Consider the following hypothetical reactions and their equilibrium constants at 75C,...
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  1. The following equilibrium constants have been determined for hydrosulfuric acid at 25ºC:

H2S(aq) ⇌ H+(aq)  +  HS(aq)            Kc = 9.5 × 10–8

HS(aq) ⇌ H+(aq)  +  S2–(aq)             K″c = 1.0 × 10–19

Calculate the equilibrium constant for the following reaction at the same temperature. 

H2S(aq) ⇌ 2H+(aq)  +  S2–(aq)

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