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The following drawing shows the association constants of three different complexes in chloroform, all three of which have three hydrogen bonds. What is the difference between the three complexes that makes the binding constants so different? Explain in detail. R. `N .R N' Ph N. Ph H H-N N H. N. R-N RO HROR K, near 10² M-1 Ka near 10ª M-1 K above 105 M-1

The following drawing shows the association constants of three different complexes in chloroform, all three of which have three hydrogen bonds. What is the difference between the three complexes that makes the binding constants so different? Explain in detail. R. `N .R N' Ph N. Ph H H-N N H. N. R-N RO HROR K, near 10² M-1 Ka near 10ª M-1 K above 105 M-1

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Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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3. The following drawing shows the association constants of three different complexes in chloroform, all three of which have three hydrogen bonds. What is the difference between the three complexes that makes the binding constants so different? Explain in detail. R. R. N. N. Ph N' N. N. Ph N. .N. H-N. N. N R-N RO HROR near Ka 102 M-1 near 104 M-1 Ko K above 105 M-1
Transcribed Image Text:3. The following drawing shows the association constants of three different complexes in chloroform, all three of which have three hydrogen bonds. What is the difference between the three complexes that makes the binding constants so different? Explain in detail. R. R. N. N. Ph N' N. N. Ph N. .N. H-N. N. N R-N RO HROR near Ka 102 M-1 near 104 M-1 Ko K above 105 M-1
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Step 1

H-Bonding is formed by electronegative elements like Fluorine, Oxygen and Nitrogen.

The stronger the H-bonds formed, greater will be the association and binding constants. 

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