The following data show the rate constant of a first-order reaction measured at several different temperatures. Construct an Arrhenius plot (In k vs 1/T) to determine the activation energy (Ea) for the reaction. You should use a graphing program (such as Excel) to construct your graph. A sketch of the graph (including the equation of the line) should be recorded in your lab notebook. temperature (K) rate constant (s) 1.68 x10-5 3.50 x10-5 4.20 x104 2.11 x103 375 400 500 600

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### Understanding the Arrhenius Equation

**Objective:**  
Analyze the rate constant of a first-order reaction at different temperatures to construct an Arrhenius plot and determine the activation energy (Ea).

**Instructions:**  
- Use a graphing program, such as Excel, to plot ln(k) versus 1/T (where T is in Kelvin). 
- Record the sketch of the graph and include the equation of the line in your lab notebook.

**Data Table:**

| Temperature (K) | Rate Constant (s⁻¹)  |
|-----------------|----------------------|
| 375             | 1.68 × 10⁻⁵          |
| 400             | 3.50 × 10⁻⁵          |
| 500             | 4.20 × 10⁻⁴          |
| 600             | 2.11 × 10⁻³          |

**Steps for Analysis:**

1. **Convert the Data:**
   - Calculate 1/T for each temperature.
   - Calculate ln(k) for each rate constant.

2. **Create the Plot:**
   - On the x-axis, plot 1/T (K⁻¹).
   - On the y-axis, plot ln(k).

3. **Analyze the Line:**
   - Determine the equation of the line from the plot.
   - The slope of the line is related to the activation energy (Ea).

**Conceptual Understanding:**

The Arrhenius equation is given by:

\[ k = A \cdot e^{-Ea/(RT)} \]

Taking the natural logarithm of both sides results in:

\[ \ln(k) = \ln(A) - \frac{Ea}{R}\left(\frac{1}{T}\right) \]

Thus, plotting ln(k) against 1/T yields a straight line, where the slope is \(-\frac{Ea}{R}\).

**Graph Analysis:**

- **Slope Calculation:** Helps to find the activation energy by multiplying the slope by the negative gas constant \(-R\).
- **Intercept Interpretation:** Corresponds to \(\ln(A)\), where A is the pre-exponential factor.

This experiment enhances comprehension of the relationship between temperature and reaction rates and develops skills in data analysis and interpretation.
Transcribed Image Text:### Understanding the Arrhenius Equation **Objective:** Analyze the rate constant of a first-order reaction at different temperatures to construct an Arrhenius plot and determine the activation energy (Ea). **Instructions:** - Use a graphing program, such as Excel, to plot ln(k) versus 1/T (where T is in Kelvin). - Record the sketch of the graph and include the equation of the line in your lab notebook. **Data Table:** | Temperature (K) | Rate Constant (s⁻¹) | |-----------------|----------------------| | 375 | 1.68 × 10⁻⁵ | | 400 | 3.50 × 10⁻⁵ | | 500 | 4.20 × 10⁻⁴ | | 600 | 2.11 × 10⁻³ | **Steps for Analysis:** 1. **Convert the Data:** - Calculate 1/T for each temperature. - Calculate ln(k) for each rate constant. 2. **Create the Plot:** - On the x-axis, plot 1/T (K⁻¹). - On the y-axis, plot ln(k). 3. **Analyze the Line:** - Determine the equation of the line from the plot. - The slope of the line is related to the activation energy (Ea). **Conceptual Understanding:** The Arrhenius equation is given by: \[ k = A \cdot e^{-Ea/(RT)} \] Taking the natural logarithm of both sides results in: \[ \ln(k) = \ln(A) - \frac{Ea}{R}\left(\frac{1}{T}\right) \] Thus, plotting ln(k) against 1/T yields a straight line, where the slope is \(-\frac{Ea}{R}\). **Graph Analysis:** - **Slope Calculation:** Helps to find the activation energy by multiplying the slope by the negative gas constant \(-R\). - **Intercept Interpretation:** Corresponds to \(\ln(A)\), where A is the pre-exponential factor. This experiment enhances comprehension of the relationship between temperature and reaction rates and develops skills in data analysis and interpretation.
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