The following are some normal modes of vibration for several molecules. In each case: • Determine the point group for the molecule • Determine how the vibration transforms under each symmetry operation of the point and assign the appropriate irreducible representation • State whether the vibration is IR active and'or Raman active (benzene): CC strotch C=C stretch "Breathing CC twist CC twist b. t. "Flexing Asymmetric CH and C-Cl stretches Asymmetric C-H and C-Ci stretches 9. Symmetric C-H and C-Ci stretches Symmetric C-H and C-CI stretches Asymmetric C-H stretches d. h. 0-
The following are some normal modes of vibration for several molecules. In each case: • Determine the point group for the molecule • Determine how the vibration transforms under each symmetry operation of the point and assign the appropriate irreducible representation • State whether the vibration is IR active and'or Raman active (benzene): CC strotch C=C stretch "Breathing CC twist CC twist b. t. "Flexing Asymmetric CH and C-Cl stretches Asymmetric C-H and C-Ci stretches 9. Symmetric C-H and C-Ci stretches Symmetric C-H and C-CI stretches Asymmetric C-H stretches d. h. 0-
Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The following are some normal modes of vibration for several molecules. In each case:
Determine the point group for the molecule
Determine how the vibration transforms under each symmetry operation of the point and assign the
appropriate irreducible representation
State whether the vibration is IR active and/or Raman active
Cote
(benzene):
C=C stretch
c=C stretch
a.
e.
"Breathing"
CC twist
C=C twist
b.
"Flexing"
Asymmetric C-H
and C-Ci stretches
Asymmetric C-H
and C-Ci stretches
C.
g.
Symmetric C-H
and C-Cl stretches
Symmetric C-H
and C-CI stretches
Asymmetric
C-H stretches
d.
h.
k.
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The following are some normal modes of vibration for several molecules. In each case:
Determine the point group for the molecule
Determine how the vibration transforms under each symmetry operation of the point and assign the
appropriate irreducible representation
State whether the vibration is IR active and/or Raman active
Cote
(benzene):
C=C stretch
c=C stretch
a.
e.
"Breathing"
CC twist
C=C twist
b.
"Flexing"
Asymmetric C-H
and C-Ci stretches
Asymmetric C-H
and C-Ci stretches
C.
g.
Symmetric C-H
and C-Cl stretches
Symmetric C-H
and C-CI stretches
Asymmetric
C-H stretches
d.
h.
k.
Page 6 of 6
3011 words
Text Predictions: On
O Focus
100%
12:01 PM
O Type here to search
12% 4
71°F
* 4) ENG
3/23/2022
19
近
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