The figure below shows Ellingham diagrams for selected metal oxides.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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QUESTION 2
The figure below shows Ellingham diagrams for selected metal oxides.
-100
de
-200
200 + O2= 2CO2
300
2N+O= 2NiO
400
C+ 02 = CO2
--500
20 + Og 2CO
Cr + O2 =Cr203
-600-
2Nb + O2= 2NDO
-700
SA+ O2 SIO2
-800
-900
2T+ O= 2TO
Change of State Element Oxide
-1000
Melting Point
M
Al+ O2=AOs
M
Boiling Point
B
B
-1100
-1200
200
400
600
800
1000
1200
Temperature ("C)
1400
1600
1800
2000
2200
2400
Fig 1
Using the Ellingham diagrams given in Fig 1, determine by calculation, whether coke (carbon)
can be used for the reduction of Cr2O3 at temperatures of 400°C, 800°C, 1200°C and 1600°C by
the following reaction:
Cr,O; (s) + 3C (s) → 2Cr (s) + 3CO (g)
[20]
AG" = RT In PO2 (kJimole Oz)
Transcribed Image Text:QUESTION 2 The figure below shows Ellingham diagrams for selected metal oxides. -100 de -200 200 + O2= 2CO2 300 2N+O= 2NiO 400 C+ 02 = CO2 --500 20 + Og 2CO Cr + O2 =Cr203 -600- 2Nb + O2= 2NDO -700 SA+ O2 SIO2 -800 -900 2T+ O= 2TO Change of State Element Oxide -1000 Melting Point M Al+ O2=AOs M Boiling Point B B -1100 -1200 200 400 600 800 1000 1200 Temperature ("C) 1400 1600 1800 2000 2200 2400 Fig 1 Using the Ellingham diagrams given in Fig 1, determine by calculation, whether coke (carbon) can be used for the reduction of Cr2O3 at temperatures of 400°C, 800°C, 1200°C and 1600°C by the following reaction: Cr,O; (s) + 3C (s) → 2Cr (s) + 3CO (g) [20] AG" = RT In PO2 (kJimole Oz)
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