The equilibrium constant for the synthesis of ammonia N2(g) + 3 H2(g) 2 2 NH3(g) has the value K = 6.78 × 10´ at 25°C. Calculate the equi- librium partial pressures of N2(g), H2(g), and NH;(g) at 25°C if the total pressure is 1.00 atm and the H:N atom ratio in the system is 3:1. (Hint: Try the approximation that PN, and PH2 < PNH; and see if the resulting equations are simplified.)

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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The equilibrium constant for the synthesis of ammonia
N2(g) + 3 H2(g) 2 2 NH3(g)
has the value K = 6.78 × 10´ at 25°C. Calculate the equi-
librium partial pressures of N2(g), H2(g), and NH;(g) at
25°C if the total pressure is 1.00 atm and the H:N atom
ratio in the system is 3:1. (Hint: Try the approximation
that PN, and PH2 < PNH; and see if the resulting equations
are simplified.)
Transcribed Image Text:The equilibrium constant for the synthesis of ammonia N2(g) + 3 H2(g) 2 2 NH3(g) has the value K = 6.78 × 10´ at 25°C. Calculate the equi- librium partial pressures of N2(g), H2(g), and NH;(g) at 25°C if the total pressure is 1.00 atm and the H:N atom ratio in the system is 3:1. (Hint: Try the approximation that PN, and PH2 < PNH; and see if the resulting equations are simplified.)
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