The electronic absorption spectra of the complexes [COC14]³, figure. LO1+

Q: Calculate the crystal field stabilizing energy (CFSE) for the complexes below. [Rh(acac)3],…

A:

Q: How many sigma bonds are present in  [Ti(H2O)6]³+?

A:

Q: The complexes [V(H2O)6]3+ and [VF6]3- are both known. Which of the two complexes would you expect to…

A: Stronger is the ligand, greater is the crystal field splitting energy, so light of higher energy…

Q: Determine the oxidation state and the dn configuration for Pt in [PtCl2(PME3)2].

A: The coordination complex is the complex in which the central metal atom is bonded with the ligand by…

Q: Co(OH2)4Cl2] Br  can exhibit both ion-ion isomerism and hydrate isomerism. True OR False

A: Given,  Co(OH2)4Cl2] Br  can exhibit both ion-ion isomerism and hydrate isomerism. The statement is:

Q: The energy of the absorption band in the electronic spectrum of the  [Ti(H2O)6]3+ complex is…

A: Given that [Ti(H2O)6]3+ has more energy of absorption band than [Ti(H2O)4]3+

Q: Give the electron configuration and the number of unpaired electrons for: (a) Cr3+; (b) Ti4+; (c)…

A: The electronic configuration of an element is the arrangement of electrons which occupy orbital…

Q: The [CrCl6]^3- ion has a maximum in its absorption spectrum at 735 nm. Calculate the crystal field…

A: Given that, the wavelength is 735 nm = 735 * 10-9 m.

Q: Identify the first row transition metal that satisfies the requirements given: a. [M(H2O)6]2+ having…

A: Transition Elements : Elements in which the last electron enters in the d-orbital. There position in…

Q: The energy of the absorption band in the electronic spectrum of the  [Ti(H2O)6]3+   complex is 20300…

A: Stability of a complex can be explained by CFSE i.e. crystal field stabilisation energy. For this…

Q: How many unpaired electrons does [Cr(OH2)6]2+ have when it has a highspin d electron configuration?

A:

Q: Write the name, the state of hybridization, the shape and the magnetic behaviour of the following…

A: Magnetic behavior has 2 terms Paramagnetic mean having unpaired electrons Diamagnetic means having…

Q: Determine deltao of the following.…

A: Two octahedral coordination complexes whose deltao is to be estimated.

Q: Which of the following species would have the shortest crystal field splitting? A) [Co(H20),J³* B)…

A:

Q: Consider the octahedral complexes of Co3+. Complete the following statements. The strong field…

A: The answer is given as follows

Q: Consider the octahedral complexes of [FeCl]³ and [Fe(CN)6]³. Explain and contrast how these…

A: Given that, two octahedral complexes are [FeCl6]3- and [Fe(CN)6]3-. We have to explain and contract…

Q: CoBr2 + 2[(C2H5)4N][Br] --> [(C2H5)4N]2[CoBr4]

A:

Q: Does [Co(NH3)4ClBr]+ have an inversion centre?

A: The objective of the question is to determine whether the complex ion Co(NH3)4ClBr+ has an inversion…

Q: How many stereoisomers exist for octahedrally shaped complex MA4(en), assuming A is monodentate…

A:

Q: [Rh(en)3]^3+, Rh^0: [Kr] 5s24d7 Illustrate the orbital splitting diagram for the complex.

A:

Q: Give an example of ambidentate ligand.

A: Ligands containing two or more donor atoms but only one coordinates with metal atom to give complex…

Q: Q3. Calculate the crystal field stabilization energy (in terms of Da) for the complexes:…

A: Applying formula of CFSE  =[ x×-0.4+y×0.6]∆° + ZP  Where  X is no of electrons in t2g  Y is no of…

Q: The maximum absorption for the complex ion [Co(NH3 )6 ] 3+ is at 470 nm. A) Predict the color of the…

A: The color of a complex depends upon the wavelength of light at which the maximum absorption occurs.…

Q: 1. Construct an MO diagram for the octahedral complex [Co(CO)6] ³+. Include the proper MO labels, AO…

A: Complex: [Co(CO)6]3+CO carbonyl is a neutral strong field ligand.Co: 3d7 4s2Co3+: 3d64s0LFSE is…

Q: Draw the crystal field diagrams for [Fe(NO2)6]4− and [FeF6]3−. State whether each complex is high…

A: In coordination complexes, metal is present at the center of the complex and ligands surround it.…

Q: Draw The Octahedral MO Diagram Of [FeCl6]3-

A:

Q: The number of unpaired electrons expected for the complex ion: [Co(OH)6]3- is: Classify as…

A: 1) Given compound: CoOH63- In this cobalt is +3 oxidation state. The electronic configuration of…

Q: [Cr(H2O)6]³* ions are pale blue-green but the chromate ion CrO,²- is intense yellow. Characterize…

A: The question is based on the concept of coordination compounds. We have been given two compounds.…

Q: Write a balanced net ionic equation for the reaction of [Cr(C₂H3O2)2(H₂O)]2 with air in the presence…

A: We have find out the answer.

Q: In the solid state, [Fe(CO)5] possesses a trigonal bipyramidal structure. Predict the mass spectrum…

A: Fe(CO)5+→Fe(CO)4+ →Fe(CO)3+ →Fe(CO)2+ →Fe(CO)+ → Fe+ m/z=195       167              139…

Q: Assign oxidation states to the transition-metal ions in the following compounds: TiO2, ZrCl4, VCl3,…

A: Oxidation state indicates the degree of oxidation for an atom in a chemical compound; it is the…

Q: Calculate the spin multiplicity for [Ni(H2O)6]2+

A:

Q: The octahedral complex ions [FeCl6]3- and [Fe(CN)6]3- are both paramagnetic, but the former is high…

A: Both the octahedral complex ions [FeCl6]3- and [Fe(CN)63- have Fe in +3 oxidation state. The number…

Q: Draw the complex structure of Co((C6H5)3PO)2(NO3)2

A: The oxidation state of cobalt is +2.

Q: Which of the following pairs are coordination isomers? a. [Pt Br2Cl2(H20)2]CO3 and [PtBr2Cl2]CO3…

A: Correct answer about coordination isomerism is given below.

Q: What are the oxidation steps of manganese in K5 [Mn (CN) 6NO], Na3MnO4 and KMnO4 compounds?

A: The oxidation state or oxidation number is the hypothetical charge that an atom would have if all…

Q: The complex ion [Co(H₂O)]³+has a maximum absorbance wavelength of 600. nm. Calculate the…

A: For the given complex CFSE = -2.4∆o  as it is d6 Low spin octahedral complex  We know , 1 KJ/mol =…

Q: Are [Co(NH3)4Cl2]Cl and [Co(NH3)4Cl]Cl2 isomers of each other? If so, what type of isomers are they?

A: Interpretation :  We have to tell whether these are isomers or not .

Q: the d-d transition of [Ti(H2O)6]3+ produces an absorption maximum at a wavelength of about 500 nm.…

A: As in this case we have d- orbital with one electron .i.e. d1 configuration. This only one electron…

Q: What simple chemical tests could you use to distinguish between the coordination complex isomers…

A: In A two water molecules are in the outside of the coordination sphere and in B there is one water…

Q: Enter the formulas for the coordination isomers of [Fe(H₂O)6] C12. Express your answers as chemical…

A: To solve this problem we have to write the coordination isomers of given complex .

Q: Draw orbital-energy splitting diagrams and use the spectro-chemical series to show the orbital…

A:

Q: Explain how experimental determination of the number of geometric isomers of [Co(NH3)4Cl]2+ would…

A: Coordination chemistry is the study of compounds having a central atom attached to certain number of…

Q: In which one of the following species does the transition metal ion have d electronic configuration?…

A:

Q: Some octahedral complexes have distorted shapes. Insome, two metal-ligand bonds that are 180° apart…

A: The structure of CuNH362+ is as follows:

Q: Calculating the LSFE of [Fe(H2O)6]Cl2, knowing that Δo = 10,400 cm–1 and P = 17,600 cm–1 Hints:…

A:

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.