The electron transfer reactions of [Co(CN),(OH2)]* with both [Co(NH3)s(SCN)]2* and[Co(NH3),(NCS)** yield [Co(CN)s(SCN)]³ as one of the products of the reaction. Thebridged intermediate can be formed by attack at two different locations on the SCN-ligand.The S-bonded linkage isomer of [Co(NH3);(SCN)]2* has a Co-S-C bond angle ofapproximately 105°, while the N-bonded linkage isomer has a Co-N-C bond angle of180°.1. Please determine each of the following for the starting complexes([Co(CN).(OH2)* and [Co(NH3)s(SCN)]²*):a. the MLXZ classification,b. the equivalent neutral classification (ENC),c. the ligand bond number (LBN),d. the valence number (VN),e. the metal dn count, andf. the total electron count (TEC).2. For the following redox reaction, please indicate whether the metal center is inertor labile towards ligand substitution.[Co(CN):(OH2)]* + [Co(NH3)s(NCS)]r* = [Co(CN):(SCN)]* + [Co(OH2);J²*3. Explain why, in the products of this reaction, one of the cobalt centers has lost allof the ammonia ligands initially attached to it.4. Draw the Lewis structure for the SCN ligand and explain the two different waysthat it can function as a bridging ligand.5. In the redox reactions between [Co(CN)s(OH2)]³ and both linkage isomers of[Co(NH3)s(SCN)]1**, [Co(CN),(SCN)]³- is one of the products formed. Please drawthe two different bridged intermediates (one that results from the reaction of eachlinkage isomer) that lead to the single S-bonded product.6. In the redox reaction between [Co(NH3)5(SCN)]²* and [Cr(OH2)eJ²*, both remoteand adjacent attack on the SCN ligand can occur, resulting in the formation of[Cr(OH2)s(NCS)]2+ and [Cr(OH2),(SCN)]²*, respectively. When [Co(NH3)s(NCS)]²*is used, only [Cr(OH,)s(SCN)]²* is formed. Please explain these results.

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The electron transfer reactions of [Co(CN)s(OH2)]³- with both [Co(NH3)s(SCN)]²* and [Co(NH3),(NCS)]²* yield [Co(CN),(SCN)]* as one of the products of the reaction. The bridged intermediate can be formed by attack at two different locations on the SCN- ligand. The S-bonded linkage isomer of [Co(NH3)s(SCN)]²+ has a Co-S-C bond angle of approximately 105°, while the N-bonded linkage isomer has a Co-N-C bond angle of 180°. 1. Please determine each of the following for the starting complexes ([Co(CN)s(OH2)]* and [Co(NH3)s(SCN)]²*): a. the MLXZ classification, b. the equivalent neutral classification (ENC), c. the ligand bond number (LBN), d. the valence number (VN), e. the metal dn count, and

The electron transfer reactions of [Co(CN)s(OH2)]³- with both [Co(NH3)s(SCN)]²* and [Co(NH3),(NCS)]²* yield [Co(CN),(SCN)]* as one of the products of the reaction. The bridged intermediate can be formed by attack at two different locations on the SCN- ligand. The S-bonded linkage isomer of [Co(NH3)s(SCN)]²+ has a Co-S-C bond angle of approximately 105°, while the N-bonded linkage isomer has a Co-N-C bond angle of 180°. 1. Please determine each of the following for the starting complexes ([Co(CN)s(OH2)]* and [Co(NH3)s(SCN)]²*): a. the MLXZ classification, b. the equivalent neutral classification (ENC), c. the ligand bond number (LBN), d. the valence number (VN), e. the metal dn count, and

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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