the Draw an orbital correlation diagram for the suprafacial-suprafacial reaction of an allyl species with an olefin to give corresponding cyclopentyl species, and establish whether the reaction is allowed or forbidden for the cation, anion, and radical. * = 0 O.

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Draw an orbital correlation diagram for the suprafacial-suprafacial reaction of an allyl species with an olefin to give the
corresponding cyclopentyl species, and establish whether the reaction is allowed or forbidden for the cation, anion, and
radical.
= 0.
5 Draw the orbital correlation diagram for the addition of ozone to ethylene to give a five-membered ring ozonide.
Is the reaction allowed or forbidden?
6. Predict the product of the following reaction. The reaction involves an intermediate (I) which sets the stereochemistry in
the product. What is this intermediate, and what is the stereochemistry of the product? (Hint: The first reaction involves
a pericyclic C-C bond cleavage.)
Ph
I
N
Heat
H₂CO₂C CO₂CH3
H_CO,C-C=C-CO,CH,
P
diene interconversion of Eq. 15.18.
Transcribed Image Text:Draw an orbital correlation diagram for the suprafacial-suprafacial reaction of an allyl species with an olefin to give the corresponding cyclopentyl species, and establish whether the reaction is allowed or forbidden for the cation, anion, and radical. = 0. 5 Draw the orbital correlation diagram for the addition of ozone to ethylene to give a five-membered ring ozonide. Is the reaction allowed or forbidden? 6. Predict the product of the following reaction. The reaction involves an intermediate (I) which sets the stereochemistry in the product. What is this intermediate, and what is the stereochemistry of the product? (Hint: The first reaction involves a pericyclic C-C bond cleavage.) Ph I N Heat H₂CO₂C CO₂CH3 H_CO,C-C=C-CO,CH, P diene interconversion of Eq. 15.18.
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