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The difluoromethylidene ligand, (M)=CF2, represents an intermediate between the Fischer carbene and Schrock carbene extremes. Account for the observation that the depicted complex C reacts rapidly at the carbenoid C with nucleophiles (Nu) and is completely unreactive towards electrophiles (E¹), while the complex D reacts at the same site rapidly with E but only slowly with Nu. CI CI PPh3 Ru PPh3 с CO :CF2 PPh3 OC. + Ru: CF2 OC PPh3 D

The difluoromethylidene ligand, (M)=CF2, represents an intermediate between the Fischer carbene and Schrock carbene extremes. Account for the observation that the depicted complex C reacts rapidly at the carbenoid C with nucleophiles (Nu) and is completely unreactive towards electrophiles (E¹), while the complex D reacts at the same site rapidly with E but only slowly with Nu. CI CI PPh3 Ru PPh3 с CO :CF2 PPh3 OC. + Ru: CF2 OC PPh3 D

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The difluoromethylidene ligand, (M)=CF2, represents an intermediate between the Fischer carbene and Schrock carbene extremes. Account for the observation that the depicted complex C reacts rapidly at the carbenoid C with nucleophiles (Nu) and is completely unreactive towards electrophiles (E¹), while the complex D reacts at the same site rapidly with E* but only slowly with Nu PPh3 CO £ CI Ru :CF₂ CI PPh3 C OC OC PPh3 Ru PPh3 D CF₂
Transcribed Image Text:The difluoromethylidene ligand, (M)=CF2, represents an intermediate between the Fischer carbene and Schrock carbene extremes. Account for the observation that the depicted complex C reacts rapidly at the carbenoid C with nucleophiles (Nu) and is completely unreactive towards electrophiles (E¹), while the complex D reacts at the same site rapidly with E* but only slowly with Nu PPh3 CO £ CI Ru :CF₂ CI PPh3 C OC OC PPh3 Ru PPh3 D CF₂
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