The diagram below shows liquids can interact with flat surfaces just as it can with capillary tubes. (a) In which of these diagrams, i or ii, do the adhesive forces between surface and liquid exceed the cohesive forces within the liquid? (b) Which of these diagrams, i or ii, represents what happens when water is on a nonpolar surface? (c) Which of these diagrams, i or ii, represents what happens when water is on a polar surface?
States of Matter
The substance that constitutes everything in the universe is known as matter. Matter comprises atoms which in turn are composed of electrons, protons, and neutrons. Different atoms combine together to give rise to molecules that act as a foundation for all kinds of substances. There are five states of matter based on their energies of attraction, namely solid, liquid, gases, plasma, and BEC (Bose-Einstein condensates).
Chemical Reactions and Equations
When a chemical species is transformed into another chemical species it is said to have undergone a chemical reaction. It consists of breaking existing bonds and forming new bonds by changing the position of electrons. These reactions are best explained using a chemical equation.
The diagram below shows liquids can interact with flat surfaces just as it can with capillary tubes.
(a) In which of these diagrams, i or ii, do the adhesive forces between surface and liquid exceed the cohesive forces within the liquid? (b) Which of these diagrams, i or ii, represents what happens when water is on a nonpolar surface? (c) Which of these diagrams, i or ii, represents what happens when water is on a polar surface?
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CHAPTER 11 Liquids and Intermolecular Forces
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Phase Changes (Section 11.4)
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11.39 Name the phase transition in each of the following situa-
tions and indicate whether it is exothermic or endothermic:
(a) Ice-cream melts at room temperature. (b) Potato slices
become crisp when fried. (c) Droplets of water appear on
the lid of a food container containing freshly baked bread.
(d) You can see your own breath on a cold day.
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11.40 Name the phase transition in each of the following situa-
tions and indicate whether it is exothermic or endother-
mic: (a) Iodine solid turns to iodine gas when it is heated.
(b) Snowflakes turn into water when they fall on an open
palm. (c) Droplets of water appear on grass in a cold humid
morning. (d) Dry ice gradually disappears when left at
room temperature for some period of time.
(i)
11.41 (a) What phase change is represented by the “heat of vapor-
ization" of a substance? (b) Is the process of vaporization
endothermic or exothermic? (c) If you compare a sub-
stance's heat of vaporization to the amount of heat released
during condensation, which one is generally larger (con-
sider the numerical value only)?
11.42 Ethyl chloride (C,H,Cl) boils at 12°C. When liquid C,H3CI
(ii)
under pressure is sprayed on a room-temperature (25 °C)
surface in air, the surface is cooled considerably. (a) What
does this observation tell us about the specific heat of
C,H5C1(g) as compared with that of C,H;Cl(1)? (b) Assume
that the heat lost by the surface is gained by ethyl chloride.
What enthalpies must you consider if you were to calculate
the final temperature of the surface?
(a) In which of these diagrams, ior ii, do the adhesive forces
between surface and liquid exceed the cohesive forces
within the liquid? (b) Which of these diagrams, i or ii, rep-
resents what happens when water is on a nonpolar surface?
(c) Which of these diagrams, i or ii, represents what hap-
pens when water is on a polar surface?
11.43 For many years drinking water has been cooled in hot cli-
11.36 Hydrazine (HaNNHa), hydrogen peroxide (HOOH), and](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ff0805737-4eac-4549-a3de-7644ead6f518%2F1eafabcd-b9ad-45e5-8829-b704f274acb4%2Fc0n1jfy_processed.png&w=3840&q=75)
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