The decomposition of crystalline N3O5 N2O5 (s) → 2NO2(g) + 02(9) is an example of a reaction that is thermodynamically favored even though it absorbs heat. At 25 °C we have the following values for the standard state enthalpy and free energy changes of the reaction: AH° = +109.6 kJ/mol AG° = -30.5 kJ/mol (a) Calculate AS° at 25 °C. (b) Why is the entropy change so favorable for this reaction? (c) Calculate AU° for this reaction at 25 °C. (d) Why is AH° greater than AU?

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The decomposition of crystalline N3O5
N2O5 (s) → 2NO2(g) + 02(9)
is an example of a reaction that is thermodynamically favored even
though it absorbs heat. At 25 °C we have the following values for the
standard state enthalpy and free energy changes of the reaction:
AH° = +109.6 kJ/mol
AG° = -30.5 kJ/mol
(a) Calculate AS° at 25 °C.
(b) Why is the entropy change so favorable for this reaction?
(c) Calculate AU° for this reaction at 25 °C.
(d) Why is AH° greater than AU?
Transcribed Image Text:The decomposition of crystalline N3O5 N2O5 (s) → 2NO2(g) + 02(9) is an example of a reaction that is thermodynamically favored even though it absorbs heat. At 25 °C we have the following values for the standard state enthalpy and free energy changes of the reaction: AH° = +109.6 kJ/mol AG° = -30.5 kJ/mol (a) Calculate AS° at 25 °C. (b) Why is the entropy change so favorable for this reaction? (c) Calculate AU° for this reaction at 25 °C. (d) Why is AH° greater than AU?
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