The decalinols A and B can be equilibrated using aluminum isopropoxide in 2-propanol (isopropyl alcohol) containing a small amount of acetone. Al[OCH(CH,),1, НО acetone ОН A B Assuming a value of AG° (equatorial to axial) for cyclohexanol is 4.0 kJ (0.95 kcal)/mol, calculate the percent of each decalinol in the equilibrium mixture at 25°C.

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The decalinols A and B can be equilibrated using aluminum isopropoxide in 2-propanol
(isopropyl alcohol) containing a small amount of acetone.
Al[OCH(CH,),1,
НО
acetone
ОН
A
B
Assuming a value of AG° (equatorial to axial) for cyclohexanol is 4.0 kJ (0.95 kcal)/mol,
calculate the percent of each decalinol in the equilibrium mixture at 25°C.
Transcribed Image Text:The decalinols A and B can be equilibrated using aluminum isopropoxide in 2-propanol (isopropyl alcohol) containing a small amount of acetone. Al[OCH(CH,),1, НО acetone ОН A B Assuming a value of AG° (equatorial to axial) for cyclohexanol is 4.0 kJ (0.95 kcal)/mol, calculate the percent of each decalinol in the equilibrium mixture at 25°C.
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