The combustion of C2H5OH is represented by the equation above and the standard entropy and enthalpy changes for the reaction are provided. When the reactants are combined at 25°C, essentially no CO2(g) or H2O(g) is produced after a few hours. Which of the diagrams above could best help explain the low yield of the reaction under these conditions, and why?   A.)Diagram 1, because it represents a reaction that is not thermodynamically favorable with ΔG°>0, regardless of its reaction rate. B.)Diagram 1, because it represents a reaction that reaches equilibrium quickly after a very small amount of the reactants is consumed. C.)Diagram 2, because it represents a reaction with a high activation energy barrier for molecules to overcome and a very slow reaction rate, even if it is thermodynamically favorable with G°<0. D.)Diagram 2, because it represents a reaction that is thermodynamically favorable with ΔH°<0, but the products formed are unstable and quickly revert to form reactants.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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The combustion of C2H5OH is represented by the equation above and the standard entropy and enthalpy changes for the reaction are provided. When the reactants are combined at 25°C, essentially no CO2(g) or H2O(g) is produced after a few hours. Which of the diagrams above could best help explain the low yield of the reaction under these conditions, and why?

 

A.)Diagram 1, because it represents a reaction that is not thermodynamically favorable with ΔG°>0, regardless of its reaction rate.

B.)Diagram 1, because it represents a reaction that reaches equilibrium quickly after a very small amount of the reactants is consumed.

C.)Diagram 2, because it represents a reaction with a high activation energy barrier for molecules to overcome and a very slow reaction rate, even if it is thermodynamically favorable with G°<0.

D.)Diagram 2, because it represents a reaction that is thermodynamically favorable with ΔH°<0, but the products formed are unstable and quickly revert to form reactants.

C2H;OH(1) + 3 O2(g) → 2 CO2(g) +3 H2O(g)
AS° = +217.7 J/(molm · K)
AH° = -1235 kJ/moln
DIAGRAM 1
DIAGRAM 2
Reactants
Reactants
Products
Products
Reaction Progress
Reaction Progress
Potential Energy
Transcribed Image Text:C2H;OH(1) + 3 O2(g) → 2 CO2(g) +3 H2O(g) AS° = +217.7 J/(molm · K) AH° = -1235 kJ/moln DIAGRAM 1 DIAGRAM 2 Reactants Reactants Products Products Reaction Progress Reaction Progress Potential Energy
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