The column was packed with 12 g of alumina. A 50:50 mixture of ferrocene and acetylferrocene was weighed on the electronic balance (total mass = 0.102 g, or 102 mg), and placed at the top of the column. Elution was first with hexane, which caused a yellow band to move down the white alumina. After the yellow fraction was collected, the eluent was replaced by TBME, which was passed through the column until the red fraction was collected. The two colored solutions were heated in a 70 °C water bath until the solvents were evaporated and colored solids were obtained. Percent recoveries for each compound were calculated, and melting points were taken. Data for the first, fastest-moving fraction: 0.045 g yellow solid, mp=170-171 °C. Data for the second, slowest-moving fraction: 0.054 g orange solid, mp= 75-80 °C.

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% Recovery of Ferrocene = (0.0459/0.102g) x 100 = 45%

% Recovery of Acetylferrocene = (0.054/0.102g) x 100 = 52.9 %

 

Question 1 : According to the data, what does % recovery means? can we say that acetylferrocene has a higher % recovery because the proportion of the amount of acetylferrocene present in the analytical portion of the 50:50 mixture is 7.9% higher than Ferrocene?????

Question 2 :Am I calculating my %recovery correctly???? 

 

THE EXPERIMENT:
The column was packed with 12 g of alumina. A 50:50 mixture of ferrocene and acetylferrocene was weighed
on the electronic balance (total mass = 0.102 g, or 102 mg), and placed at the top of the column. Elution was
first with hexane, which caused a yellow band to move down the white alumina. After the yellow fraction was
collected, the eluent was replaced by TBME, which was passed through the column until the red fraction was
collected. The two colored solutions were heated in a 70 °C water bath until the solvents were evaporated and
colored solids were obtained. Percent recoveries for each compound were calculated, and melting points were
taken.
Data for the first, fastest-moving fraction: 0.045 g yellow solid, mp= 170-171 °C.
Data for the second, slowest-moving fraction: 0.054 g orange solid, mp = 75-80 °C.
Transcribed Image Text:THE EXPERIMENT: The column was packed with 12 g of alumina. A 50:50 mixture of ferrocene and acetylferrocene was weighed on the electronic balance (total mass = 0.102 g, or 102 mg), and placed at the top of the column. Elution was first with hexane, which caused a yellow band to move down the white alumina. After the yellow fraction was collected, the eluent was replaced by TBME, which was passed through the column until the red fraction was collected. The two colored solutions were heated in a 70 °C water bath until the solvents were evaporated and colored solids were obtained. Percent recoveries for each compound were calculated, and melting points were taken. Data for the first, fastest-moving fraction: 0.045 g yellow solid, mp= 170-171 °C. Data for the second, slowest-moving fraction: 0.054 g orange solid, mp = 75-80 °C.
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