The column was packed with 12 g of alumina. A 50:50 mixture of ferrocene and acetylferrocene was weighed on the electronic balance (total mass = 0.102 g, or 102 mg), and placed at the top of the column. Elution was first with hexane, which caused a yellow band to move down the white alumina. After the yellow fraction was collected, the eluent was replaced by TBME, which was passed through the column until the red fraction was collected. The two colored solutions were heated in a 70 °C water bath until the solvents were evaporated and colored solids were obtained. Percent recoveries for each compound were calculated, and melting points were taken. Data for the first, fastest-moving fraction: 0.045 g yellow solid, mp=170-171 °C. Data for the second, slowest-moving fraction: 0.054 g orange solid, mp= 75-80 °C.
The column was packed with 12 g of alumina. A 50:50 mixture of ferrocene and acetylferrocene was weighed on the electronic balance (total mass = 0.102 g, or 102 mg), and placed at the top of the column. Elution was first with hexane, which caused a yellow band to move down the white alumina. After the yellow fraction was collected, the eluent was replaced by TBME, which was passed through the column until the red fraction was collected. The two colored solutions were heated in a 70 °C water bath until the solvents were evaporated and colored solids were obtained. Percent recoveries for each compound were calculated, and melting points were taken. Data for the first, fastest-moving fraction: 0.045 g yellow solid, mp=170-171 °C. Data for the second, slowest-moving fraction: 0.054 g orange solid, mp= 75-80 °C.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
% Recovery of Ferrocene = (0.0459/0.102g) x 100 = 45%
% Recovery of Acetylferrocene = (0.054/0.102g) x 100 = 52.9 %
Question 1 : According to the data, what does % recovery means? can we say that acetylferrocene has a higher % recovery because the proportion of the amount of acetylferrocene present in the analytical portion of the 50:50 mixture is 7.9% higher than Ferrocene?????
Question 2 :Am I calculating my %recovery correctly????

Transcribed Image Text:THE EXPERIMENT:
The column was packed with 12 g of alumina. A 50:50 mixture of ferrocene and acetylferrocene was weighed
on the electronic balance (total mass = 0.102 g, or 102 mg), and placed at the top of the column. Elution was
first with hexane, which caused a yellow band to move down the white alumina. After the yellow fraction was
collected, the eluent was replaced by TBME, which was passed through the column until the red fraction was
collected. The two colored solutions were heated in a 70 °C water bath until the solvents were evaporated and
colored solids were obtained. Percent recoveries for each compound were calculated, and melting points were
taken.
Data for the first, fastest-moving fraction: 0.045 g yellow solid, mp= 170-171 °C.
Data for the second, slowest-moving fraction: 0.054 g orange solid, mp = 75-80 °C.
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 4 steps with 4 images

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning

Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY