The clock reaction reaction: H2O2 + 3I- + 2H+ → I3- + 2H2O occurs through the following mechanism. H2O2 + H+ ↔ H3O2+ (fast equilibrium K1 ) H3O2+ + I- → H2O + HOI (slow k2 ) HOI + I- → OH- + I2 (fast k3) OH- + H+ → H2O (fast k4) I2 + I- → I3- (fast k5) What is the rate law for this reaction?
The clock reaction reaction: H2O2 + 3I- + 2H+ → I3- + 2H2O occurs through the following mechanism. H2O2 + H+ ↔ H3O2+ (fast equilibrium K1 ) H3O2+ + I- → H2O + HOI (slow k2 ) HOI + I- → OH- + I2 (fast k3) OH- + H+ → H2O (fast k4) I2 + I- → I3- (fast k5) What is the rate law for this reaction?
Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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The clock reaction reaction: H2O2 + 3I- + 2H+ → I3- + 2H2O occurs through the following mechanism.
- H2O2 + H+ ↔ H3O2+ (fast equilibrium K1 )
- H3O2+ + I- → H2O + HOI (slow k2 )
- HOI + I- → OH- + I2 (fast k3)
- OH- + H+ → H2O (fast k4)
- I2 + I- → I3- (fast k5)
What is the rate law for this reaction?
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