The Clausius- Clapeyron equation on the assumption that the enthalpy of vaporization is independent of temperature in the range of interest. (a) Theenthalpy of vaporization of water is 40.656 kJ mol-1 at its normal boiling temperature, 373 K. Assuming that the enthalpy of vaporization does not vary with temperature, calculate the vapour pressure of water at 308 K. (b) Derive an improved version of the equation on the basis that the enthalpy of vaporization has the form ΔvapH =a+ bT. (c) For water in the range298- 373 K, a= 57.373 kJ mol-1 and b = -44.801 J K-1 mol- 1. Use your improved version of the Clausius-Clapeyron equation to calculate a more reliable value for the vapour pressure of water at 308 K.
The Clausius- Clapeyron equation on the assumption that the enthalpy of vaporization is independent of temperature in the range of interest. (a) Theenthalpy of vaporization of water is 40.656 kJ mol-1 at its normal boiling temperature, 373 K. Assuming that the enthalpy of vaporization does not vary with temperature, calculate the vapour pressure of water at 308 K. (b) Derive an improved version of the equation on the basis that the enthalpy of vaporization has the form ΔvapH =a+ bT. (c) For water in the range298- 373 K, a= 57.373 kJ mol-1 and b = -44.801 J K-1 mol- 1. Use your improved version of the Clausius-Clapeyron equation to calculate a more reliable value for the vapour pressure of water at 308 K.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
The Clausius- Clapeyron equation on the assumption that the enthalpy of vaporization is independent of temperature in the range of interest. (a) The
enthalpy of vaporization of water is 40.656 kJ mol-1 at its normal boiling temperature, 373 K. Assuming that the enthalpy of vaporization does not vary with temperature, calculate the vapour pressure of water at 308 K. (b) Derive an improved version of the equation on the basis that the enthalpy of vaporization has the form ΔvapH =a+ bT. (c) For water in the range
298- 373 K, a= 57.373 kJ mol-1 and b = -44.801 J K-1 mol- 1. Use your improved version of the Clausius-Clapeyron equation to calculate a more reliable value for the vapour pressure of water at 308 K.
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 5 steps with 3 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY