The chromium product of the redox reaction of [Co(NH3)5CI]2+ with [Cr(H2O)6]2+ is [Cr(H2O);CI]2*. This demonstrates that the reaction proceeds by a process in which: a Co(lll)-bound chloride ligand enters the coordination sphere of the Cr(l) species before electron transfer. a chloride ligand is lost from the Co(lll) center before association with the Cr(Il) species and before electron transfer. a free chloride ion replaces H20 in [Cr(H2O)6]²+ after electron transfer. the inner coordination sphere of both reactants remain intact during electron transfer.

The chromium product of the redox reaction of [Co(NH3)5CI]2+ with [Cr(H2O)6]2+ is [Cr(H2O);CI]2*. This demonstrates that the reaction proceeds by a process in which: a Co(lll)-bound chloride ligand enters the coordination sphere of the Cr(l) species before electron transfer. a chloride ligand is lost from the Co(lll) center before association with the Cr(Il) species and before electron transfer. a free chloride ion replaces H20 in [Cr(H2O)6]²+ after electron transfer. the inner coordination sphere of both reactants remain intact during electron transfer.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

The chromium product of the redox reaction of [Co(NH3)5CI]²+ with
[Cr(H2O)6]2* is [Cr(H2O);CI]2+. This demonstrates that the reaction proceeds
by a process in which:
a Co(lll)-bound chloride ligand enters the coordination sphere of the Cr(Il) species
before electron transfer.
a chloride ligand is lost from the Co(ll) center before association with the Cr(II)
species and before electron transfer.
a free chloride ion replaces H20 in [Cr(H2O)6]2+ after electron transfer.
the inner coordination sphere of both reactants remain intact during electron
transfer.

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