the box to the right of each molecule, draw a constitutional (structural) isomer of it Fr: 0:

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Chapter20: Organic Chemistry
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### Constitutional (Structural) Isomers of Organic Molecules

**Instruction:** In the box to the right of each molecule, draw a constitutional (structural) isomer of it.

1. **First Molecule (Left to Right)**
   - **Structure:** The molecule features a three-carbon chain with a bromine (Br) atom attached to the first carbon.
   - **Box for Isomer:** Draw an alternate structural isomer of the given molecule in the empty box provided.

2. **Second Molecule**
   - **Structure:** The molecule is a four-membered ring with an oxygen (O) atom, highlighting the structure as an epoxide.
   - **Box for Isomer:** Draw a structural isomer in the box; this should represent a different connectivity but the same molecular formula.

3. **Third Molecule**
   - **Structure:** The structure consists of a three-carbon chain with an amine group (NH₂) attached to the second carbon (middle carbon).
   - **Box for Isomer:** Draw a structural isomer of this molecule in the provided box, displaying a different connectivity for the same molecular formula.

### Detailed Explanation

**Diagram Overview:**
- The given structures all feature a specific organic molecule with functional groups such as halogens (Br), oxygen in a cyclic form, and amines (NH₂).
- The task is to draw a constitutional isomer for each, which is a compound with the same molecular formula but different connectivity of atoms.

**Concept Review:**
- **Constitutional Isomers:** These are compounds that have the same molecular formula but their atoms are arranged differently in the molecule. This results in different physical and chemical properties.

### Common Strategies for Drawing Isomers:
1. **Rearrange Carbon Chains:** Change the length or branching of carbon chains while preserving the molecular formula.
2. **Shift Functional Groups:** Move functional groups to different positions along the carbon chain or ring.
3. **Change Ring Structures:** For cyclic molecules, consider different possible ring sizes or positions of heteroatoms (e.g., O in the case of epoxides).

This practice helps in understanding and visualizing how different structures with the same molecular formula can exist, illustrating the concept of isomerism in organic chemistry.
Transcribed Image Text:### Constitutional (Structural) Isomers of Organic Molecules **Instruction:** In the box to the right of each molecule, draw a constitutional (structural) isomer of it. 1. **First Molecule (Left to Right)** - **Structure:** The molecule features a three-carbon chain with a bromine (Br) atom attached to the first carbon. - **Box for Isomer:** Draw an alternate structural isomer of the given molecule in the empty box provided. 2. **Second Molecule** - **Structure:** The molecule is a four-membered ring with an oxygen (O) atom, highlighting the structure as an epoxide. - **Box for Isomer:** Draw a structural isomer in the box; this should represent a different connectivity but the same molecular formula. 3. **Third Molecule** - **Structure:** The structure consists of a three-carbon chain with an amine group (NH₂) attached to the second carbon (middle carbon). - **Box for Isomer:** Draw a structural isomer of this molecule in the provided box, displaying a different connectivity for the same molecular formula. ### Detailed Explanation **Diagram Overview:** - The given structures all feature a specific organic molecule with functional groups such as halogens (Br), oxygen in a cyclic form, and amines (NH₂). - The task is to draw a constitutional isomer for each, which is a compound with the same molecular formula but different connectivity of atoms. **Concept Review:** - **Constitutional Isomers:** These are compounds that have the same molecular formula but their atoms are arranged differently in the molecule. This results in different physical and chemical properties. ### Common Strategies for Drawing Isomers: 1. **Rearrange Carbon Chains:** Change the length or branching of carbon chains while preserving the molecular formula. 2. **Shift Functional Groups:** Move functional groups to different positions along the carbon chain or ring. 3. **Change Ring Structures:** For cyclic molecules, consider different possible ring sizes or positions of heteroatoms (e.g., O in the case of epoxides). This practice helps in understanding and visualizing how different structures with the same molecular formula can exist, illustrating the concept of isomerism in organic chemistry.
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