The boiling point of an alcohol is 77.870 ᵒC. at 1atm. When 13.64 g of an unknown compound was dissolved in 235.1 g of this alcohol, the solution boiled at 79.228 ᵒC. Kb of this alcohol is 1.160 ᵒC/m. What is the molar mass of the unknown compound?

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12. The boiling point of an alcohol is 77.870 C. at 1atm. When 13.64 g of an unknown compound was dissolved in 235.1 g of this alcohol, the solution boiled at 79.228 C. Kb of this alcohol is 1.160 C/m. What is the molar mass of the unknown compound?

Expert Solution
Change in boiling point / Elevation in Boiling point

∆Tb = Tfinal - Tinitial  = 79.228 - 77.870 =  1.358° C

Molality of solution

Molality, m = number of moles of unknown solute ÷ weight of solvent (kg)

m = (W ÷ Mwt) ÷ 0.2351

m = (13.64 ÷ Mwt) ÷ 0.2351   (equation 1)

 

 

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