The boiling point of an alcohol is 77.870 ᵒC. at 1atm. When 13.64 g of an unknown compound was dissolved in 235.1 g of this alcohol, the solution boiled at 79.228 ᵒC. Kb of this alcohol is 1.160 ᵒC/m. What is the molar mass of the unknown compound?
The boiling point of an alcohol is 77.870 ᵒC. at 1atm. When 13.64 g of an unknown compound was dissolved in 235.1 g of this alcohol, the solution boiled at 79.228 ᵒC. Kb of this alcohol is 1.160 ᵒC/m. What is the molar mass of the unknown compound?
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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12. The boiling point of an alcohol is 77.870 ᵒC. at 1atm. When 13.64 g of an unknown compound was dissolved in 235.1 g of this alcohol, the solution boiled at 79.228 ᵒC. Kb of this alcohol is 1.160 ᵒC/m. What is the molar mass of the unknown compound?
Expert Solution
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Change in boiling point / Elevation in Boiling point
∆Tb = Tfinal - Tinitial = 79.228 - 77.870 = 1.358° C
Molality of solution
Molality, m = number of moles of unknown solute ÷ weight of solvent (kg)
m = (W ÷ Mwt) ÷ 0.2351
m = (13.64 ÷ Mwt) ÷ 0.2351 (equation 1)
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