4.The binding constants between the two amines shown and porphyrin monomer and dimer were measured in CH,Cl2solution. Account for the relative binding constants obtained and estimate the effective molarities for the secondbinding constants within the dimer cavity.N=Zn2N-N=Zn2+ROORN-Zn2+3.0 x 1032.5 x 107H2N.NH21.4 x 1045.5 x 1065. Compound 7 can undergo isomerization upon photo or thermo stimulation.NH2NH2NN.NN.N.R'N'N'Rtrans-7cis-7Draw the structure of the dimers formed between the different geometrical isomers of 7 in CHCI3. Also rank thestability of the different dimers with explanation.

Stability of the chelating agent or compound is determined by the entropy, higher the chelation…

The binding constants between the two amines shown and porphyrin monomer and dimer were measured in CH₂Cl₂ solution. Account for the relative binding constants obtained and estimate the effective molarities for the second binding constants within the dimer cavity.

The binding constants between the two amines shown and porphyrin monomer and dimer were measured in CH₂Cl₂ solution. Account for the relative binding constants obtained and estimate the effective molarities for the second binding constants within the dimer cavity.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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