The arsenic in a 2.345g sample of a pesticide was converted to H 3 AsO4 by suitable treatment. The acid was then neutralized, and 60.00 ml of 0.06781M AgNO 3 was added to precipitate the arsenic quantitatively as Ag 3 AsO4. The excess Ag+ in the filtrate and washings from the precipitate was titrated with 15.27 ml of 0.123 M KSCN; the reaction was Ag+ + SCN- → AgSCN(s) Calculate the percentage As 2 O 3 in the sample.
The arsenic in a 2.345g sample of a pesticide was converted to H 3 AsO4 by suitable treatment. The acid was then neutralized, and 60.00 ml of 0.06781M AgNO 3 was added to precipitate the arsenic quantitatively as Ag 3 AsO4. The excess Ag+ in the filtrate and washings from the precipitate was titrated with 15.27 ml of 0.123 M KSCN; the reaction was Ag+ + SCN- → AgSCN(s) Calculate the percentage As 2 O 3 in the sample.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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- The arsenic in a 2.345g sample of a pesticide was converted to H 3 AsO4 by suitable treatment.
The acid was then neutralized, and 60.00 ml of 0.06781M AgNO 3 was added to precipitate the
arsenic quantitatively as Ag 3 AsO4. The excess Ag+ in the filtrate and washings from the
precipitate was titrated with 15.27 ml of 0.123 M KSCN; the reaction was
Ag+ + SCN- → AgSCN(s)
Calculate the percentage As 2 O 3 in the sample.
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