The approximate empirical expression for variation of molar heat capacity at constant pressure Cpm with temperature is given by Cpm a + bT + T2 [4] Calculate the change in molar enthalpy AH, when the given gas is heated from 25 °C to 500 °C using the expression above. The constants a, b, and c are available in Table 2B.1. AT= 500 – 25 = 475K for Br2 : a-37.32 b=0.50×10³K! c=-1.26×10°K?

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  • Compare DHm from (1) and (2) and comment.
The approximate empirical expression for variation of molar heat capacity at
constant pressure Cm with temperature is given by
Cp.m = a + bT +
T2
[4] Calculate the change in molar enthalpy AHm when the given gas is heated
from 25 °C to 500 °C using the expression above. The constants a, b, and c
are available in Table 2B.1.
AT= 500 – 25 = 475K
for Br2 : a-37.32 b=0.50×10³K!
c=-1.26x10 K?
[5] Evaluate Cp.m at 298 K using the above expression. What is AHm using this
constant value of Cp.m?
[6] Compare AHm from (1) and (2) and comment.
Transcribed Image Text:The approximate empirical expression for variation of molar heat capacity at constant pressure Cm with temperature is given by Cp.m = a + bT + T2 [4] Calculate the change in molar enthalpy AHm when the given gas is heated from 25 °C to 500 °C using the expression above. The constants a, b, and c are available in Table 2B.1. AT= 500 – 25 = 475K for Br2 : a-37.32 b=0.50×10³K! c=-1.26x10 K? [5] Evaluate Cp.m at 298 K using the above expression. What is AHm using this constant value of Cp.m? [6] Compare AHm from (1) and (2) and comment.
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