مه h. H H3C Br H CH3 Br CH3 CH3 and and H H3C H Br Br CH3 CH3 CH3

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Are the following constitutional, identical, enantiomers, or diastereomers?

### Alkenes with Different Substituents

Here we examine the structural diagrams of alkenes with different substituents. These diagrams are useful in understanding the spatial arrangement and isomerism in organic compounds.

**g.** The structural formula of an alkene with the substituents - hydrogen (H), methyl group (CH₃), bromine (Br), and another methyl group (CH₃) on a double-bonded carbon (C=C):
- Left Structure: H | C | CH₃
  - Left Bottom: H₃C
  - Right Bottom: Br
- Right Structure: H | C=C | Br
  - Left Bottom: H₃C
  - Right Bottom: CH₃

**h.** The structural formula of another alkene with the substituents - bromine (Br), methyl group (CH₃), hydrogen (H), and another methyl group (CH₃) on a double-bonded carbon (C=C):
- Left Structure: Br | C | CH₃
  - Left Bottom: H
  - Right Bottom: CH₃
- Right Structure: H | C=C | CH₃
  - Left Bottom: Br
  - Right Bottom: CH₃

These diagrams illustrate different placements of the substituents around the carbon-carbon double bond, indicating different isomers of the same molecular formula. Isomerism, in this case, arises due to the different possible orientations of the groups around the double bond.
Transcribed Image Text:### Alkenes with Different Substituents Here we examine the structural diagrams of alkenes with different substituents. These diagrams are useful in understanding the spatial arrangement and isomerism in organic compounds. **g.** The structural formula of an alkene with the substituents - hydrogen (H), methyl group (CH₃), bromine (Br), and another methyl group (CH₃) on a double-bonded carbon (C=C): - Left Structure: H | C | CH₃ - Left Bottom: H₃C - Right Bottom: Br - Right Structure: H | C=C | Br - Left Bottom: H₃C - Right Bottom: CH₃ **h.** The structural formula of another alkene with the substituents - bromine (Br), methyl group (CH₃), hydrogen (H), and another methyl group (CH₃) on a double-bonded carbon (C=C): - Left Structure: Br | C | CH₃ - Left Bottom: H - Right Bottom: CH₃ - Right Structure: H | C=C | CH₃ - Left Bottom: Br - Right Bottom: CH₃ These diagrams illustrate different placements of the substituents around the carbon-carbon double bond, indicating different isomers of the same molecular formula. Isomerism, in this case, arises due to the different possible orientations of the groups around the double bond.
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In the answer key, g is a configurational isomer.

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