The amount of I−3(aq)I3−⁡(aq) in a solution can be determined by titration with a solution containing a known concentration of S2O2−3(aq)S2⁢O32−⁡(aq) (thiosulfate ion). The determination is based on the net ionic equation   2S2O2−3(aq)+I−3(aq)⟶S4O2−6(aq)+3I−(aq)2⁢S2⁢O32−⁡(aq)+I3−⁡(aq)⟶S4⁢O62−⁡(aq)+3⁢I−⁡(aq)   Given that it requires 43.9 mL43.9 mL of 0.310 M Na2S2O3(aq)0.310 M Na2⁢S2⁢O3⁡(aq) to titrate a 10.0 mL10.0 mL sample of I−3(aq),I3−⁡(aq), calculate the molarity of I−3(aq)I3−⁡(aq) in the solution.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter3: Chemical Reactions
Section3.11: Stoichiometry In Aqueous Solutions
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The amount of I−3(aq)I3−⁡(aq) in a solution can be determined by titration with a solution containing a known concentration of S2O2−3(aq)S2⁢O32−⁡(aq) (thiosulfate ion). The determination is based on the net ionic equation

 

2S2O2−3(aq)+I−3(aq)⟶S4O2−6(aq)+3I−(aq)2⁢S2⁢O32−⁡(aq)+I3−⁡(aq)⟶S4⁢O62−⁡(aq)+3⁢I−⁡(aq)

 

Given that it requires 43.9 mL43.9 mL of 0.310 M Na2S2O3(aq)0.310 M Na2⁢S2⁢O3⁡(aq) to titrate a 10.0 mL10.0 mL sample of I−3(aq),I3−⁡(aq), calculate the molarity of I−3(aq)I3−⁡(aq) in the solution.

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