Calcium levels in blood can be determined by adding oxalate ion to precipitate calcium oxalate, CaC2O4, followed by dissolving the precipitate in aqueous acid and titrating the resulting oxalic acid (H₂C₂O4) with KMnO4: 5H₂C2O4 (aq) + 2MnO4¯(aq) + 6H+ (aq) → 10CO₂ (g) + 2Mn²+ (aq) + 8H₂O(1) Part A How many milligrams of Ca²+ are present in 10.0 mL of blood if 21.40 mL of 0.000967 M KMnO4 solution is needed for the titration? Express your answer in milligrams to three significant figures. 195| ΑΣΦ Mass of Ca²+ = 0.332 ? mg
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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