The amino acid glycine, C2H5NO2, is one of the compounds used by the body to make proteins. The equation for its combustion is 4C2H5NO2(s) + 9O2(5) → 8CO2(g) +10H2O(1) +2N2(g) For each mole of glycine that burns, 973.49 kJ of heat is liberated. Use this information, plus values of AH° for the products of combustion, to calculate AH for glycine. AH° = i ! kJ/mol

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In the recovery of iron from iron ore, the reduction of the ore is actually accomplished by reactions involving carbon monoxide. Use the
following thermochemical equations,
Fe,O3() + 3CO(g) 2Fe(s) + 3CO,(g)
AH° = -28 kJ
3Fe,O3() + CO(g) 2Fe,O4(0) + CO,(g)
AH° = -59 kJ
Fe,O4(6) + CO(g)-
3FeO(s) + CO,(g)
AH° = +38 kJ
The AH° for the reaction
FeO() + CO(g) Fe(s) + CO2(g)
is -16.8 kJ. Use this data and the data in the following table to calculate the value of AH° for FeO.
Standard Enthalpies of Formation of Typical Substances
AH; (KI mol-1)
AH (KI mol-1)
AH (KI mol-)
)
AH; (KI mol-1)
Substance
Substance
Substance
Substance
Ag(s)
H,O,(/)
-187.6
CH(g)
-84.667
NO(g)
90.37
AgBr()
-100.4
HBrg)
-36
CH,OH(/)
-277.63
NO,(g)
33.8
AgC()
- 127.0
HC(g)
-92.30
Ca(s)
N,0(g)
81.57
AIG)
HI(g)
26.6
CaBrz6)
-682.8
N,Odg)
9.67
Al,O,()
-1669.8
HNO,()
-173.2
CaCO)
- 1207
N,0;(g)
11
Ct) (graphite)
H,SO,)
-811.32
CaCl()
-795.0
Na(s)
CO(e)
-110.5
HC,H,0,)
NaHCO,6)
-947.7
-487.0
CaO()
--635.5
CO:)
-393.5
Hg(/)
Ca(OH)20)
-986.59
Na,CO,()
-1131
CH,(g)
-74.848
Hg(g)
60.84
CaSO,()
- 1432.7
NaCl(s)
-411.0
CH,C(g)
-82.0
1,0)
CasO, H,0()
- 1575.2
NAOH())
-426.8
CHI(g)
Na SO,)
14.2
K()
CaSO, 2H,0G)
- 2021.1
-1384.5
CH,OH()
CO(NH),) (urea)
CONH(ag)
-238.6
KCI)
-435.89
Ch(e)
-333.19
K,SO,()
- 1433.7
Fe(s)
Pb(s)
-391.2
Na(g)
Fe,O,4)
-822.2
PbO()
-219.2
CH(g)
226.75
NH3(g)
-46.19
H2(g)
CH.(g)
52.284
NH,CI()
-315.4
H,O(g)
-241.8
So-(g)
-296.9
H,O)
-285.9
So,(g)
-395.2
Express the answer in units of kilojoules per mole.
AH;° = i
kJ/mol
Transcribed Image Text:In the recovery of iron from iron ore, the reduction of the ore is actually accomplished by reactions involving carbon monoxide. Use the following thermochemical equations, Fe,O3() + 3CO(g) 2Fe(s) + 3CO,(g) AH° = -28 kJ 3Fe,O3() + CO(g) 2Fe,O4(0) + CO,(g) AH° = -59 kJ Fe,O4(6) + CO(g)- 3FeO(s) + CO,(g) AH° = +38 kJ The AH° for the reaction FeO() + CO(g) Fe(s) + CO2(g) is -16.8 kJ. Use this data and the data in the following table to calculate the value of AH° for FeO. Standard Enthalpies of Formation of Typical Substances AH; (KI mol-1) AH (KI mol-1) AH (KI mol-) ) AH; (KI mol-1) Substance Substance Substance Substance Ag(s) H,O,(/) -187.6 CH(g) -84.667 NO(g) 90.37 AgBr() -100.4 HBrg) -36 CH,OH(/) -277.63 NO,(g) 33.8 AgC() - 127.0 HC(g) -92.30 Ca(s) N,0(g) 81.57 AIG) HI(g) 26.6 CaBrz6) -682.8 N,Odg) 9.67 Al,O,() -1669.8 HNO,() -173.2 CaCO) - 1207 N,0;(g) 11 Ct) (graphite) H,SO,) -811.32 CaCl() -795.0 Na(s) CO(e) -110.5 HC,H,0,) NaHCO,6) -947.7 -487.0 CaO() --635.5 CO:) -393.5 Hg(/) Ca(OH)20) -986.59 Na,CO,() -1131 CH,(g) -74.848 Hg(g) 60.84 CaSO,() - 1432.7 NaCl(s) -411.0 CH,C(g) -82.0 1,0) CasO, H,0() - 1575.2 NAOH()) -426.8 CHI(g) Na SO,) 14.2 K() CaSO, 2H,0G) - 2021.1 -1384.5 CH,OH() CO(NH),) (urea) CONH(ag) -238.6 KCI) -435.89 Ch(e) -333.19 K,SO,() - 1433.7 Fe(s) Pb(s) -391.2 Na(g) Fe,O,4) -822.2 PbO() -219.2 CH(g) 226.75 NH3(g) -46.19 H2(g) CH.(g) 52.284 NH,CI() -315.4 H,O(g) -241.8 So-(g) -296.9 H,O) -285.9 So,(g) -395.2 Express the answer in units of kilojoules per mole. AH;° = i kJ/mol
The amino acid glycine, C2H5NO2, is one of the compounds used by the body to make proteins. The equation for its combustion is
4C2H5NO2(s) + 902(g) → 8CO2(g) +10H2O(1) +2N2(g)
For each mole of glycine that burns, 973.49 kJ of heat is liberated. Use this information, plus values of AH° for the products of
combustion, to calculate AH° for glycine.
ΔΗ-
i
! kJ/mol
Transcribed Image Text:The amino acid glycine, C2H5NO2, is one of the compounds used by the body to make proteins. The equation for its combustion is 4C2H5NO2(s) + 902(g) → 8CO2(g) +10H2O(1) +2N2(g) For each mole of glycine that burns, 973.49 kJ of heat is liberated. Use this information, plus values of AH° for the products of combustion, to calculate AH° for glycine. ΔΗ- i ! kJ/mol
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