The addition of HBr to buta-1,3-diene results in 1,2-addition at cold temperatures and 1,4-addition at warm temperatures. If the 1,2-adduct is first formed at cold temperatures and then warmed up, the 1,4-adduct is formed, as shown here. Draw a mechanism for this H H Нeat Br Br 1,2-Adduct 1,4-Adduct isomerization.
The addition of HBr to buta-1,3-diene results in 1,2-addition at cold temperatures and 1,4-addition at warm temperatures. If the 1,2-adduct is first formed at cold temperatures and then warmed up, the 1,4-adduct is formed, as shown here. Draw a mechanism for this H H Нeat Br Br 1,2-Adduct 1,4-Adduct isomerization.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:The addition of HBr to buta-1,3-diene results in
1,2-addition at cold temperatures and 1,4-addition at
warm temperatures. If the 1,2-adduct is first formed at
cold temperatures and then warmed up, the 1,4-adduct
is formed, as shown here. Draw a mechanism for this
H
H
Нeat
Br
Br
1,2-Adduct
1,4-Adduct
isomerization.
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