The activation energy for the gas phase isomerization of dimethyl maleate is 111 kJ. cis-CH3 OOCCH=CHCOOCH3 → trans-CH3 OOCCH=CHCOOCH3 The rate constant at 697 K is 6.36 x 10 4 -1. The rate constant will be at 746 K.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
The activation energy for the gas phase isomerization of dimethyl maleate is 111 kJ.
cis-CH3OOCCH=CHCOOCH3 → trans-CH3 OOCCH=CHCOOCH3
The rate constant at 697 K is 6.36 × 10-4 s-1. The rate constant will be
S
at 746 K.
Transcribed Image Text:The activation energy for the gas phase isomerization of dimethyl maleate is 111 kJ. cis-CH3OOCCH=CHCOOCH3 → trans-CH3 OOCCH=CHCOOCH3 The rate constant at 697 K is 6.36 × 10-4 s-1. The rate constant will be S at 746 K.
Expert Solution
Step 1: Given

cis-CH3OOCCH=CHCOOCH3 ----> trans-CH3OOCCH=CHCOOCH3

Rate constant (k)Temperature (T)
k1 = 6.36 × 10-4 s-1T1 = 697 K
k2 = ? s-1T2 = 746 K

Activation energy (Ea) = 111 kJ = 111 × 1000 J = 111000 J

Note

Universal gas constant (R) = 8.314 J/mol.K


steps

Step by step

Solved in 3 steps

Blurred answer
Knowledge Booster
Rate Laws
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY