The activation energy for the gas phase isomerization of dimethyl maleate is 111 kJ. cis-CH3 OOCCH=CHCOOCH3 → trans-CH3 OOCCH=CHCOOCH3 The rate constant at 697 K is 6.36 x 10 4 -1. The rate constant will be at 746 K.
The activation energy for the gas phase isomerization of dimethyl maleate is 111 kJ. cis-CH3 OOCCH=CHCOOCH3 → trans-CH3 OOCCH=CHCOOCH3 The rate constant at 697 K is 6.36 x 10 4 -1. The rate constant will be at 746 K.
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
Transcribed Image Text:The activation energy for the gas phase isomerization of dimethyl maleate is 111 kJ.
cis-CH3OOCCH=CHCOOCH3 → trans-CH3 OOCCH=CHCOOCH3
The rate constant at 697 K is 6.36 × 10-4 s-1. The rate constant will be
S
at 746 K.
Expert Solution

Step 1: Given
cis-CH3OOCCH=CHCOOCH3 ----> trans-CH3OOCCH=CHCOOCH3
Rate constant (k) | Temperature (T) |
k1 = 6.36 × 10-4 s-1 | T1 = 697 K |
k2 = ? s-1 | T2 = 746 K |
Activation energy (Ea) = 111 kJ = 111 × 1000 J = 111000 J
Note:
Universal gas constant (R) = 8.314 J/mol.K
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