The acetylacetone ion forms very stable complexes with many metallic ions. It acts as a bidentate ligand, coordi- nating to the metal at two adjacent positions. Suppose that one of the CH3 groups of the ligand is replaced by a CF; group, as shown here: н Trifluoromethyl acetylacetonate CF-Ç (ffac) C-CH3 :Ö: :0: Sketch all possible isomers for the complex with three tfac ligands on cobalt(III). (You can use the symbol to repre- sent the ligand.)
The acetylacetone ion forms very stable complexes with many metallic ions. It acts as a bidentate ligand, coordi- nating to the metal at two adjacent positions. Suppose that one of the CH3 groups of the ligand is replaced by a CF; group, as shown here: н Trifluoromethyl acetylacetonate CF-Ç (ffac) C-CH3 :Ö: :0: Sketch all possible isomers for the complex with three tfac ligands on cobalt(III). (You can use the symbol to repre- sent the ligand.)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:The acetylacetone ion forms very stable complexes with
many metallic ions. It acts as a bidentate ligand, coordi-
nating to the metal at two adjacent positions. Suppose that
one of the CH3 groups of the ligand is replaced by a CF;
group, as shown here:
н
Trifluoromethyl
acetylacetonate CF-Ç
(ffac)
C-CH3
:Ö:
:0:
Sketch all possible isomers for the complex with three tfac
ligands on cobalt(III). (You can use the symbol to repre-
sent the ligand.)
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